Chemical Bath Co-deposited ZnS Film Prepared from Different Zinc Salts: ZnSO4-Zn(CH3COO)(2), Zn(NO3)(2)-Zn(CH3COO)(2), or ZnSO4-Zn(NO3)(2) | |
Liu, Tingzhi; Li, Yangyang; Ke, Huan; Qian, Yuhai; Duo, Shuwang; Hong, Yanli; Sun, Xinyuan; swduo@imr.ac.cn | |
2016 | |
发表期刊 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
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ISSN | 1005-0302 |
卷号 | 32期号:3页码:207-217 |
摘要 | ZnSO4-Zn(CH3COO)(2), Zn(NO3)(2)-Zn(CH3COO)(2), ZnSO4-Zn(NO3)(2), ZnSO4, Zn(NO3)(2) or Zn(CH3COO)(2) have been used as zinc sources to prepare ZnS thin films by chemical bath deposition and co-deposition methods. Zn(NO3)(2) or/and Zn(CH3COO)(2) is/are favorable for cluster by cluster deposition process while ZnSO4 favors ion by ion deposition process regardless of concentration ratios of ZnSO4. However, Zn(NO3)(2) affects the nucleation density of ZnS nuclei on the substrate. ZnS thin films deposited from ZnSO4-Zn(CH3COO)(2) are not only more homogeneous and compact, but also have higher growth rate and adhesion on to the glass substrate. The cubic ZnS films are obtained after only single deposition. The average transmission of films from S6, S7, S8, S9 and S1 for 2 and 2.5 h is greater than 85% in visible region. Compared with the film from S6 (112 nm), the film from S7 is not only thicker (125 nm), but also more transparent. The band gaps of the films deposited from S6, S7, S8, S9 and S1 for 2 and 2.5 h range from 3.88 to 3.98 eV. The effects of anions from different zinc salts are discussed in detail. Copyright (C) 2015, The editorial office of Journal of Materials Science & Technology. Published by Elsevier Limited. All rights reserved. |
部门归属 | [liu, tingzhi ; li, yangyang ; ke, huan ; duo, shuwang ; hong, yanli ; sun, xinyuan] jiangxi sci & technol normal univ, jiangxi key lab surface engn, nanchang 330013, peoples r china ; [qian, yuhai ; duo, shuwang] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china |
关键词 | Thin Film Chemical Synthesis Electron Microscopy Mechanical Properties Optical Properties |
资助者 | National Natural Science Foundation of China [50963003]; Natural Science Foundation of Jiangxi Province [2010GZC0044]; Foundation of Jiangxi Educational Commission [GJJ14558]; Project of Jiangxi Youth Scientist [20122BCB23031] |
收录类别 | sci |
语种 | 英语 |
WOS记录号 | WOS:000370814900003 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/74665 |
专题 | 中国科学院金属研究所 |
通讯作者 | swduo@imr.ac.cn |
推荐引用方式 GB/T 7714 | Liu, Tingzhi,Li, Yangyang,Ke, Huan,et al. Chemical Bath Co-deposited ZnS Film Prepared from Different Zinc Salts: ZnSO4-Zn(CH3COO)(2), Zn(NO3)(2)-Zn(CH3COO)(2), or ZnSO4-Zn(NO3)(2)[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2016,32(3):207-217. |
APA | Liu, Tingzhi.,Li, Yangyang.,Ke, Huan.,Qian, Yuhai.,Duo, Shuwang.,...&swduo@imr.ac.cn.(2016).Chemical Bath Co-deposited ZnS Film Prepared from Different Zinc Salts: ZnSO4-Zn(CH3COO)(2), Zn(NO3)(2)-Zn(CH3COO)(2), or ZnSO4-Zn(NO3)(2).JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,32(3),207-217. |
MLA | Liu, Tingzhi,et al."Chemical Bath Co-deposited ZnS Film Prepared from Different Zinc Salts: ZnSO4-Zn(CH3COO)(2), Zn(NO3)(2)-Zn(CH3COO)(2), or ZnSO4-Zn(NO3)(2)".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 32.3(2016):207-217. |
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