Development of Cu foam-based Ni catalyst for solar thermal reforming of methane with carbon dioxide

IMR OpenIR

	Development of Cu foam-based Ni catalyst for solar thermal reforming of methane with carbon dioxide
	Qi, Jianzhong; Sun, Yanping; Xie, Zongli; Collins, Mike; Du, Hao; Xiong, Tianying; Yanping.Sun@csiro.au
	2015
发表期刊	JOURNAL OF ENERGY CHEMISTRY
ISSN	2095-4956
卷号	24 期号:6 页码:786-793
摘要	Using solar energy to produce syngas via the endothermic reforming of methane has been extensively investigated at the laboratory- and pilot plant-scales as a promising method of storing solar energy. One of the challenges to scaling up this process in a tubular reformer is to improve the reactor's performance, which is limited by mass and heat transfer issues. High thermal conductivity Cu foam was therefore used as a substrate to improve the catalyst's thermal conductivity during solar reforming. We also developed a method to coat the foam with the catalytically active component NiMg3AlOx. The Cu foam-based NiMg3AlOx performs better than catalysts supported on SiSiC foam, which is currently used as a substrate for solar-reforming catalysts, at high gas hourly space velocity (>= 400,000 mL/(g.h)) or at low reaction temperatures (<= 720 degrees C). The presence of a gamma-Al2O3 intermediate layer improves the adhesion between the catalyst and substrate as well as the catalytic activity. (C) 2015 Science Press and Dalian Institute of Chemical Physics. All rights reserved.
部门归属	[qi, jianzhong ; du, hao ; xiong, tianying] chinese acad sci, inst met res, shenyang 110016, liaoning, peoples r china ; [sun, yanping ; collins, mike] csiro energy flagship, newcastle, nsw 2300, australia ; [xie, zongli] csiro mfg flagship, clayton, vic 3169, australia
关键词	Cu Foam-based Ni Catalyst Monolithic Catalyst Solar Thermal Reforming Of Methane
资助者	CSIRO Energy Flagship; Chinese Scholarship Council
收录类别	sci
语种	英语
WOS记录号	WOS:000366542300018
引用统计	被引频次：16[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/74717
专题	中国科学院金属研究所
通讯作者	Yanping.Sun@csiro.au
推荐引用方式 GB/T 7714	Qi, Jianzhong,Sun, Yanping,Xie, Zongli,et al. Development of Cu foam-based Ni catalyst for solar thermal reforming of methane with carbon dioxide[J]. JOURNAL OF ENERGY CHEMISTRY,2015,24(6):786-793.
APA	Qi, Jianzhong.,Sun, Yanping.,Xie, Zongli.,Collins, Mike.,Du, Hao.,...&Yanping.Sun@csiro.au.(2015).Development of Cu foam-based Ni catalyst for solar thermal reforming of methane with carbon dioxide.JOURNAL OF ENERGY CHEMISTRY,24(6),786-793.
MLA	Qi, Jianzhong,et al."Development of Cu foam-based Ni catalyst for solar thermal reforming of methane with carbon dioxide".JOURNAL OF ENERGY CHEMISTRY 24.6(2015):786-793.