Electrochemical Study on the Inhibition Effect of Phenanthroline and Its Cobalt Complex as Corrosion Inhibitors for Mild Steel | |
Liu, Xia; Okafor, Peter C.; Jiang, Bin; Hu, Hongxiang; Zheng, Yugui; laura-lx@163.com; ygzheng@imr.ac.cn | |
2015 | |
发表期刊 | JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
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ISSN | 1059-9495 |
卷号 | 24期号:9页码:3599-3606 |
摘要 | The corrosion inhibition effect of phenanthroline (Phen) and its cobalt complex (CoPhen) on the corrosion of carbon steel in sulphuric acid solutions was studied using potentiodynamic polarization and electrochemical impedance spectroscopy techniques at 20, 30, and 40 A degrees C. Scanning electron microscopy techniques were used to characterize the mild steel surface. The results indicate that the compounds inhibit the corrosion of mild steel in H2SO4 solutions through a predominant physical adsorption following the Langmuir adsorption isotherm. Polarization curves suggest that the complex and ligand are mixed-type inhibitors. The efficiency of the inhibitors is concentration- and temperature-dependent and follows the trend CoPhen > Phen. |
部门归属 | [liu, xia] shenyang univ chem technol, dept appl chem, shenyang 110142, peoples r china ; [okafor, peter c.] univ calabar, dept pure & appl chem, corros & electrochem res grp, calabar, nigeria ; [jiang, bin ; hu, hongxiang ; zheng, yugui] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china |
关键词 | Adsorption Cobalt Complex Corrosion Inhibition Mild Steel Phenanthroline Sulphuric Acid |
收录类别 | sci |
语种 | 英语 |
WOS记录号 | WOS:000360014000041 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/74814 |
专题 | 中国科学院金属研究所 |
通讯作者 | laura-lx@163.com; ygzheng@imr.ac.cn |
推荐引用方式 GB/T 7714 | Liu, Xia,Okafor, Peter C.,Jiang, Bin,et al. Electrochemical Study on the Inhibition Effect of Phenanthroline and Its Cobalt Complex as Corrosion Inhibitors for Mild Steel[J]. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,2015,24(9):3599-3606. |
APA | Liu, Xia.,Okafor, Peter C..,Jiang, Bin.,Hu, Hongxiang.,Zheng, Yugui.,...&ygzheng@imr.ac.cn.(2015).Electrochemical Study on the Inhibition Effect of Phenanthroline and Its Cobalt Complex as Corrosion Inhibitors for Mild Steel.JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,24(9),3599-3606. |
MLA | Liu, Xia,et al."Electrochemical Study on the Inhibition Effect of Phenanthroline and Its Cobalt Complex as Corrosion Inhibitors for Mild Steel".JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE 24.9(2015):3599-3606. |
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