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Electrochemical Study on the Inhibition Effect of Phenanthroline and Its Cobalt Complex as Corrosion Inhibitors for Mild Steel
Liu, Xia; Okafor, Peter C.; Jiang, Bin; Hu, Hongxiang; Zheng, Yugui; laura-lx@163.com; ygzheng@imr.ac.cn
2015
发表期刊JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
ISSN1059-9495
卷号24期号:9页码:3599-3606
摘要The corrosion inhibition effect of phenanthroline (Phen) and its cobalt complex (CoPhen) on the corrosion of carbon steel in sulphuric acid solutions was studied using potentiodynamic polarization and electrochemical impedance spectroscopy techniques at 20, 30, and 40 A degrees C. Scanning electron microscopy techniques were used to characterize the mild steel surface. The results indicate that the compounds inhibit the corrosion of mild steel in H2SO4 solutions through a predominant physical adsorption following the Langmuir adsorption isotherm. Polarization curves suggest that the complex and ligand are mixed-type inhibitors. The efficiency of the inhibitors is concentration- and temperature-dependent and follows the trend CoPhen > Phen.
部门归属[liu, xia] shenyang univ chem technol, dept appl chem, shenyang 110142, peoples r china ; [okafor, peter c.] univ calabar, dept pure & appl chem, corros & electrochem res grp, calabar, nigeria ; [jiang, bin ; hu, hongxiang ; zheng, yugui] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china
关键词Adsorption Cobalt Complex Corrosion Inhibition Mild Steel Phenanthroline Sulphuric Acid
收录类别sci
语种英语
WOS记录号WOS:000360014000041
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/74814
专题中国科学院金属研究所
通讯作者laura-lx@163.com; ygzheng@imr.ac.cn
推荐引用方式
GB/T 7714
Liu, Xia,Okafor, Peter C.,Jiang, Bin,et al. Electrochemical Study on the Inhibition Effect of Phenanthroline and Its Cobalt Complex as Corrosion Inhibitors for Mild Steel[J]. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,2015,24(9):3599-3606.
APA Liu, Xia.,Okafor, Peter C..,Jiang, Bin.,Hu, Hongxiang.,Zheng, Yugui.,...&ygzheng@imr.ac.cn.(2015).Electrochemical Study on the Inhibition Effect of Phenanthroline and Its Cobalt Complex as Corrosion Inhibitors for Mild Steel.JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,24(9),3599-3606.
MLA Liu, Xia,et al."Electrochemical Study on the Inhibition Effect of Phenanthroline and Its Cobalt Complex as Corrosion Inhibitors for Mild Steel".JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE 24.9(2015):3599-3606.
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