Enhanced photocatalytic hydrogen generation of mesoporous rutile TiO2 single crystal with wholly exposed {111} facets | |
Wu, Tingting; Kang, Xiangdong; Kadi, Mohammad W.; Ismail, Iqbal; Liu, Gang; Cheng, Hui-Ming; mkadi@kau.edu.sa; gangliu@imr.ac.cn | |
2015 | |
发表期刊 | CHINESE JOURNAL OF CATALYSIS
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ISSN | 0253-9837 |
卷号 | 36期号:12页码:2103-2108 |
摘要 | The development of semiconductor photocatalysts with highly reactive facets exposed has great potential to improve their photocatalytic reactivity. We report the synthesis of mesoporous rutile TiO2 single crystals with tunable ratios of {110} and {111} facets through the seeded-template hydrothermal method. With increasing the amount of morphology controlling agent NaF, the facet ratio of {111} to {110} increases, and eventually the mesoporous ruble TiO2 single crystals with wholly exposed {111} reactive facets are obtained. The resultant faceted mesoporous single crystals exhibit a superior photocatalytic performance of hydrogen evolution to mesoporous single crystals with a large percentage of thermodynamically stable {110} facets, as well as the solid rutile single crystals. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
部门归属 | [wu, tingting ; kang, xiangdong ; liu, gang ; cheng, hui-ming] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, liaoning, peoples r china ; [kadi, mohammad w. ; ismail, iqbal ; cheng, hui-ming] king abdulaziz univ, fac sci, dept chem, jeddah 21589, saudi arabia |
关键词 | Titania Photocatalyst Mesoporous Single-crystal Hydrogen Generation |
资助者 | National Basic Research Program of China (973 Program) [2014CB239401]; National Natural Science Foundation of China [51422210, 51172243]; King Abdulaziz University [50-130-35-HiCi] |
收录类别 | sci |
语种 | 英语 |
WOS记录号 | WOS:000366960200006 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/74825 |
专题 | 中国科学院金属研究所 |
通讯作者 | mkadi@kau.edu.sa; gangliu@imr.ac.cn |
推荐引用方式 GB/T 7714 | Wu, Tingting,Kang, Xiangdong,Kadi, Mohammad W.,et al. Enhanced photocatalytic hydrogen generation of mesoporous rutile TiO2 single crystal with wholly exposed {111} facets[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(12):2103-2108. |
APA | Wu, Tingting.,Kang, Xiangdong.,Kadi, Mohammad W..,Ismail, Iqbal.,Liu, Gang.,...&gangliu@imr.ac.cn.(2015).Enhanced photocatalytic hydrogen generation of mesoporous rutile TiO2 single crystal with wholly exposed {111} facets.CHINESE JOURNAL OF CATALYSIS,36(12),2103-2108. |
MLA | Wu, Tingting,et al."Enhanced photocatalytic hydrogen generation of mesoporous rutile TiO2 single crystal with wholly exposed {111} facets".CHINESE JOURNAL OF CATALYSIS 36.12(2015):2103-2108. |
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