| Heteropoly Acid/Nitrogen Functionalized Onion-like Carbon Hybrid Catalyst for Ester Hydrolysis Reactions | |
| Liu, Wei; Qi, Wei; Guo, Xiaoling; Su, Dangsheng; wqi@imr.ac.cn; dssu@imr.ac.cn | |
| 2016 | |
| Source Publication | CHEMISTRY-AN ASIAN JOURNAL
 |
| ISSN | 1861-4728 |
| Volume | 11Issue:4Pages:491-497 |
| Abstract | A novel heteropoly acid (HPA)/nitrogen functionalized onion-like carbon (NOLC) hybrid catalyst was synthesized through supramolecular (electrostatic and hydrogen bond) interactions between the two components. The chemical structure and acid strength of the HPA/NOLC hybrid have been fully characterized by thermogravimetric analysis, IR spectroscopy, X-ray photoelectron spectroscopy, NH3 temperature-programmed desorption and acid-base titration measurements. The proposed method for the fabrication of the HPA/NOLC hybrid catalyst is a universal strategy for different types of HPAs to meet various requirements of acidic or redox catalysis. The hydrophobic environment of NOLC effectively prevents the deactivation of HPA in an aqueous system, and the combination of uniformly dispersed HPA clusters and the synergistic effect between NOLC and HPA significantly promotes its activity in ester hydrolysis reactions, which is higher than that of bare PWA as homogeneous catalyst. The kinetics of the hydrolysis reactions indicate that the aggregation status of the catalyst particles has great influence on the apparent activity. |
| description.department | [liu, wei ; qi, wei ; guo, xiaoling ; su, dangsheng] chinese acad sci, shenyang natl lab mat sci, inst met res, 72 wenhua rd, shenyang 110016, peoples r china ; [guo, xiaoling] dalian univ technol, lab adv mat & catalyt engn, dalian 116024, peoples r china |
| Keyword | Heterogeneous Catalysis Heteropoly Acid Hydrolysis Onion-like Carbon Support |
| Funding Organization | NSFC of China [21303226, 21133010, 51221264, 21261160487]; "Strategic Priority Research Program" of the Chinese Academy of Sciences; China Postdoctoral Science Foundation [2012M520651] |
| Indexed By | sci |
| Language | 英语 |
| WOS ID | WOS:000371494500011 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/74876 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | wqi@imr.ac.cn; dssu@imr.ac.cn |
| Recommended Citation GB/T 7714 | Liu, Wei,Qi, Wei,Guo, Xiaoling,et al. Heteropoly Acid/Nitrogen Functionalized Onion-like Carbon Hybrid Catalyst for Ester Hydrolysis Reactions[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(4):491-497. |
| APA | Liu, Wei,Qi, Wei,Guo, Xiaoling,Su, Dangsheng,wqi@imr.ac.cn,&dssu@imr.ac.cn.(2016).Heteropoly Acid/Nitrogen Functionalized Onion-like Carbon Hybrid Catalyst for Ester Hydrolysis Reactions.CHEMISTRY-AN ASIAN JOURNAL,11(4),491-497. |
| MLA | Liu, Wei,et al."Heteropoly Acid/Nitrogen Functionalized Onion-like Carbon Hybrid Catalyst for Ester Hydrolysis Reactions".CHEMISTRY-AN ASIAN JOURNAL 11.4(2016):491-497. |
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