Hierarchical ZSM-5/SiC nano-whisker/SiC foam composites: Preparation and application in MTP reactions

IMR OpenIR

	Hierarchical ZSM-5/SiC nano-whisker/SiC foam composites: Preparation and application in MTP reactions
	Jiao, Yilai; Yang, Xiaodan; Jiang, Chunhai; Tian, Chong; Yang, Zhenming; Zhang, Jinsong; jshzhang@imr.ac.cn
	2015
发表期刊	JOURNAL OF CATALYSIS
ISSN	0021-9517
卷号	332 页码:70-76
摘要	A hierarchical composite catalyst composed of a ZSM-5 coating on SiC nano-whiskers that grew on SiC foam supports was designed and synthesized to simultaneously improve the zeolite loading and mass transfer of both the reactants and products in the methanol-to-propylene (MTP) reaction. SiC nano-whiskers were first grown on SiC foam supports by a chemical vapor deposition method to construct a hierarchical porous structure on the struts. ZSM-5 type zeolite crystals with high coverage were then hydrothermally grown on the SiC nano-whiskers after their surface was properly modified with zeolite precursor gel. In this way, the mass loading of the zeolite coating and mass transfer property, the two key factors that hinder the catalytic properties of the ZSM-5/SiC foam composite reported in our previous work, were enhanced, which in turn substantially improved the stability and selectivity of the obtained ZSM-5/SiC nano-whisker/SiC foam composites in MTP reaction as compared with those of the ZSM-5/SiC foam composites and ZSM-5 pellets. (C) 2015 Elsevier Inc. All rights reserved.
部门归属	[jiao, yilai ; yang, xiaodan ; jiang, chunhai ; tian, chong ; yang, zhenming ; zhang, jinsong] chinese acad sci, inst met res, shenyang 110016, peoples r china
关键词	Composite Catalyst Zsm-5 Coating Sic Nano-whiskers Sic Foam Supports Mtp
资助者	National 863 Program of China [2012AA030304]
收录类别	sci
语种	英语
WOS记录号	WOS:000366073500008
引用统计	被引频次：70[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/74880
专题	中国科学院金属研究所
通讯作者	jshzhang@imr.ac.cn
推荐引用方式 GB/T 7714	Jiao, Yilai,Yang, Xiaodan,Jiang, Chunhai,et al. Hierarchical ZSM-5/SiC nano-whisker/SiC foam composites: Preparation and application in MTP reactions[J]. JOURNAL OF CATALYSIS,2015,332:70-76.
APA	Jiao, Yilai.,Yang, Xiaodan.,Jiang, Chunhai.,Tian, Chong.,Yang, Zhenming.,...&jshzhang@imr.ac.cn.(2015).Hierarchical ZSM-5/SiC nano-whisker/SiC foam composites: Preparation and application in MTP reactions.JOURNAL OF CATALYSIS,332,70-76.
MLA	Jiao, Yilai,et al."Hierarchical ZSM-5/SiC nano-whisker/SiC foam composites: Preparation and application in MTP reactions".JOURNAL OF CATALYSIS 332(2015):70-76.