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High Reversible Lithium Storage Capacity and Structural Changes of Fe2O3 Nanoparticles Confined inside Carbon Nanotubes
Yu, Wan-Jing; Zhang, Lili; Hou, Peng-Xiang; Li, Feng; Liu, Chang; Cheng, Hui-Ming; cliu@imr.ac.cn; cheng@imr.ac.cn
2016
Source PublicationADVANCED ENERGY MATERIALS
ISSN1614-6832
Volume6Issue:3Pages:-
AbstractThe structural evolution of electrochemically prelithiated Fe2O3 nanoparticles confined in carbon nanotubes (CNTs) during lithium insertion/extraction is studied by in situ transmission electron microscopy. It is found that the aggregation and coarsening of Fe core-containing Li2O (Fe@Li2O) nanograins formed during the charge process are prevented by the spatial restriction of the CNTs. A high reversible capacity of 2071 mA h g(-1) for the encapsulated Fe2O3 nanoparticles in CNTs is demonstrated when the material is used as the anode of lithium ion batteries. This is the highest reversible capacity ever reported for an Fe2O3 electrode. The significantly improved lithium storage capacity of the Fe2O3 nanoparticles is attributed to the extra lithium storage due to the enhanced interfacial lithium storage and reversible reaction of LiOH to form LiH and solid-electrolyte-interphase conversion originating from the nanoconfinement of CNTs as well as the very small particle size of the Fe@Li2O nanograins and their good electrical contact with CNTs.
description.department[yu, wan-jing ; zhang, lili ; hou, peng-xiang ; li, feng ; liu, chang ; cheng, hui-ming] chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china
KeywordCarbon Nanotubes Confinement Effects Fe2o3 Nanoparticles In Situ Tem Lithium-ion Batteries
Funding OrganizationMinistry of Science and Technology of China [2011CB932601, 2011CB932604]; National Natural Science Foundation of China [51102242, 51172241, 51221264, 51272257]; Chinese Academy of Sciences [KGZD-EW-T06]
Indexed Bysci
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/74883
Collection中国科学院金属研究所
Corresponding Authorcliu@imr.ac.cn; cheng@imr.ac.cn
Recommended Citation
GB/T 7714
Yu, Wan-Jing,Zhang, Lili,Hou, Peng-Xiang,et al. High Reversible Lithium Storage Capacity and Structural Changes of Fe2O3 Nanoparticles Confined inside Carbon Nanotubes[J]. ADVANCED ENERGY MATERIALS,2016,6(3):-.
APA Yu, Wan-Jing.,Zhang, Lili.,Hou, Peng-Xiang.,Li, Feng.,Liu, Chang.,...&cheng@imr.ac.cn.(2016).High Reversible Lithium Storage Capacity and Structural Changes of Fe2O3 Nanoparticles Confined inside Carbon Nanotubes.ADVANCED ENERGY MATERIALS,6(3),-.
MLA Yu, Wan-Jing,et al."High Reversible Lithium Storage Capacity and Structural Changes of Fe2O3 Nanoparticles Confined inside Carbon Nanotubes".ADVANCED ENERGY MATERIALS 6.3(2016):-.
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