Investigation of the reaction progress between stannous chloride and zirconium in molten LiCl-KCl

IMR OpenIR

	Investigation of the reaction progress between stannous chloride and zirconium in molten LiCl-KCl
	Cai, Yanqing; Liu, Hongxia; Xu, Qian; Song, Qiushi; Liu, Huijun; qianxu201@mail.neu.edu.cn
	2015
发表期刊	RSC ADVANCES
ISSN	2046-2069
卷号	5 期号:40 页码:31648-31655
摘要	LiCl-KCl-ZrCl4 melt was prepared by an in situ displacement reaction between SnCl2 and Zr in LiCl-KCl melt at 773 K, and the progress of the reaction between SnCl2 and Zr was also investigated by dynamic electrochemical measurements, such as cyclic voltammetry, square wave voltammetry and open circuit chronopotentiometry. The results reveal that the concentration of Zr(IV) increases gradually and reaches a maximum value with the reaction time increasing from 0 to 210 min, while the concentration of Sn(II) decreases gradually and drops below the detection limit. In addition, the chemical analyses of Zr(IV) and Sn(II) in the melt at various times were also carried out and the results are in good agreement with those of the electrochemical measurements. Finally, LiCl-KCl-ZrCl4 melts with a low concentration of Sn(II) (<0.01 wt%) were obtained, when the reaction time was prolonged to 210 min.
部门归属	[cai, yanqing ; liu, hongxia ; song, qiushi] northeastern univ, sch mat sci & met, shenyang 110004, peoples r china ; [xu, qian] shanghai univ, sch mat sci & engn, shanghai 200072, peoples r china ; [liu, huijun] chinese acad sci, inst met res, lab corros & protect, shenyang 110016, peoples r china
资助者	National Natural Science Foundation of China [51174055]
收录类别	sci
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/74931
专题	中国科学院金属研究所
通讯作者	qianxu201@mail.neu.edu.cn
推荐引用方式 GB/T 7714	Cai, Yanqing,Liu, Hongxia,Xu, Qian,et al. Investigation of the reaction progress between stannous chloride and zirconium in molten LiCl-KCl[J]. RSC ADVANCES,2015,5(40):31648-31655.
APA	Cai, Yanqing,Liu, Hongxia,Xu, Qian,Song, Qiushi,Liu, Huijun,&qianxu201@mail.neu.edu.cn.(2015).Investigation of the reaction progress between stannous chloride and zirconium in molten LiCl-KCl.RSC ADVANCES,5(40),31648-31655.
MLA	Cai, Yanqing,et al."Investigation of the reaction progress between stannous chloride and zirconium in molten LiCl-KCl".RSC ADVANCES 5.40(2015):31648-31655.