Palladium Supported on Nanodiamonds as an Efficient Catalyst for the Hydrogenating Deamination of Benzonitrile and Related Compounds

IMR OpenIR

	Palladium Supported on Nanodiamonds as an Efficient Catalyst for the Hydrogenating Deamination of Benzonitrile and Related Compounds
	Gupta, Neeraj; Ding, Yuxiao; Feng, Zhenbao; Su, Dangsheng; dssu@imr.ac.cn
	2016
发表期刊	CHEMCATCHEM
ISSN	1867-3880
卷号	8 期号:5 页码:922-928
摘要	Palladium nanoparticles were successfully prepared on a nanodiamond (ND) support and used for the hydrogenating deamination of benzonitrile, aromatic imines, and amines for the first time. The developed methodology was further used for the insitu conversion of aldehydes into hydrocarbons, including a biomass-derived model compound. The activity of the catalyst was compared with palladium supported on activated carbon (AC) under identical conditions and the performance of Pd/ND was found to be superior to Pd/AC. The origin of the difference in the catalytic performance was considered. Finally, an attempt has been made to understand the mechanism through the identification of the side products by GCMS analysis.
部门归属	[gupta, neeraj ; ding, yuxiao ; feng, zhenbao ; su, dangsheng] chinese acad sci, inst met res, shenyang natl lab mat sci, catalysis div, shenyang 110016, peoples r china
关键词	Amines Benzonitrile Biomass Conversion Lignin Palladium
资助者	Chinese Academy of Sciences (CAS)
收录类别	sci
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/75050
专题	中国科学院金属研究所
通讯作者	dssu@imr.ac.cn
推荐引用方式 GB/T 7714	Gupta, Neeraj,Ding, Yuxiao,Feng, Zhenbao,et al. Palladium Supported on Nanodiamonds as an Efficient Catalyst for the Hydrogenating Deamination of Benzonitrile and Related Compounds[J]. CHEMCATCHEM,2016,8(5):922-928.
APA	Gupta, Neeraj,Ding, Yuxiao,Feng, Zhenbao,Su, Dangsheng,&dssu@imr.ac.cn.(2016).Palladium Supported on Nanodiamonds as an Efficient Catalyst for the Hydrogenating Deamination of Benzonitrile and Related Compounds.CHEMCATCHEM,8(5),922-928.
MLA	Gupta, Neeraj,et al."Palladium Supported on Nanodiamonds as an Efficient Catalyst for the Hydrogenating Deamination of Benzonitrile and Related Compounds".CHEMCATCHEM 8.5(2016):922-928.