Preparation of AgCl Nanocubes and Their Application as Efficient Photoinitiators in the Polymerization of N-Isopropylacrylamide

IMR OpenIR

	Preparation of AgCl Nanocubes and Their Application as Efficient Photoinitiators in the Polymerization of N-Isopropylacrylamide
	Yang, Ying; Zhao, Yan; Yan, Yukun; Wang, Yanli; Guo, Changyou; Zhang, Jinsong; jshzhang@imr.ac.cn
	2015
发表期刊	JOURNAL OF PHYSICAL CHEMISTRY B
ISSN	1520-6106
卷号	119 期号:46 页码:14807-14813
摘要	Uniform AgCl nanocubes with an average size of about 360 nm have been synthesized. Under UV illumination, a layer of silver nanoparticles with surface plasmon resonance was produced and covered the surface of AgCl particles in a short time, and the Ag/AgCl particles remained quite stable as shown in XRD patterns. The as-synthesized AgCl particles were tried for the first time as photoinitiator to polymerize N-isopropylacrylamide under UV-irradiation, and a high efficiency and conversion rate were realized. The structure of the polymers was studied by FTIR spectrophotometer. The results of turbidimetric method showed that the polymers were temperature sensitive and their lower critical solution temperature was about 33 degrees C. The effects of photoinitiators concentration, monomers concentration, and irradiation time on the polymer yield were investigated. The reaction mechanism was discussed by using salicylic acid as scavengers of hydroxyl radicals and conducting the reaction under oxygen atmosphere, respectively. The results proved that hydroxyl radicals were essential to chain initiation.
部门归属	[yang, ying ; zhao, yan ; yan, yukun ; wang, yanli ; guo, changyou ; zhang, jinsong] chinese acad sci, inst met res, shenyang 110016, peoples r china
收录类别	sci
语种	英语
WOS记录号	WOS:000365463200024
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/75075
专题	中国科学院金属研究所
通讯作者	jshzhang@imr.ac.cn
推荐引用方式 GB/T 7714	Yang, Ying,Zhao, Yan,Yan, Yukun,et al. Preparation of AgCl Nanocubes and Their Application as Efficient Photoinitiators in the Polymerization of N-Isopropylacrylamide[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2015,119(46):14807-14813.
APA	Yang, Ying.,Zhao, Yan.,Yan, Yukun.,Wang, Yanli.,Guo, Changyou.,...&jshzhang@imr.ac.cn.(2015).Preparation of AgCl Nanocubes and Their Application as Efficient Photoinitiators in the Polymerization of N-Isopropylacrylamide.JOURNAL OF PHYSICAL CHEMISTRY B,119(46),14807-14813.
MLA	Yang, Ying,et al."Preparation of AgCl Nanocubes and Their Application as Efficient Photoinitiators in the Polymerization of N-Isopropylacrylamide".JOURNAL OF PHYSICAL CHEMISTRY B 119.46(2015):14807-14813.