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The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction
Sun, Xiaoyan; Xu, Junyuan; Ding, Yuxiao; Zhang, Bingsen; Feng, Zhenbao; Su, Dang Sheng; dssu@imr.ac.cn
2015
Source PublicationCHEMSUSCHEM
ISSN1864-5631
Volume8Issue:17Pages:2872-2876
AbstractTwo kinds of phosphorus-modified onion-like carbons dominated by C-O-P bonds and C-P bonds were fabricated and further used as catalysts in the oxygen reduction reaction (ORR). The results show that the bonding state of phosphorus has a significant effect on the ORR catalytic activity. The formation of C-O-P bonds improves ORR activity, whereas C-P bonds play an adverse role in stabilizing the key intermediates during the ORR owing to the distorted graphitic structure, as confirmed by the work function value.
description.department[sun, xiaoyan ; xu, junyuan ; ding, yuxiao ; zhang, bingsen ; feng, zhenbao ; su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china
KeywordDoping Electrocatalysis Onion-like Carbon Oxygen Reduction Phosphorus
Funding OrganizationMinistry of Science and Technology (MOST) [2011CBA00504]; National Natural Science Foundation of China (NSFC) [21133010, 21103203, 51221264, 21261160487, 21203215]; "Strategic Priority Research Program" of the Chinese Academy of Sciences [XDA09030103]
Indexed Bysci
Language英语
WOS IDWOS:000360915800009
Citation statistics
Cited Times:26[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/75188
Collection中国科学院金属研究所
Corresponding Authordssu@imr.ac.cn
Recommended Citation
GB/T 7714
Sun, Xiaoyan,Xu, Junyuan,Ding, Yuxiao,et al. The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction[J]. CHEMSUSCHEM,2015,8(17):2872-2876.
APA Sun, Xiaoyan.,Xu, Junyuan.,Ding, Yuxiao.,Zhang, Bingsen.,Feng, Zhenbao.,...&dssu@imr.ac.cn.(2015).The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction.CHEMSUSCHEM,8(17),2872-2876.
MLA Sun, Xiaoyan,et al."The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction".CHEMSUSCHEM 8.17(2015):2872-2876.
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