The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction | |
Sun, Xiaoyan; Xu, Junyuan; Ding, Yuxiao; Zhang, Bingsen; Feng, Zhenbao; Su, Dang Sheng; dssu@imr.ac.cn | |
2015 | |
Source Publication | CHEMSUSCHEM
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ISSN | 1864-5631 |
Volume | 8Issue:17Pages:2872-2876 |
Abstract | Two kinds of phosphorus-modified onion-like carbons dominated by C-O-P bonds and C-P bonds were fabricated and further used as catalysts in the oxygen reduction reaction (ORR). The results show that the bonding state of phosphorus has a significant effect on the ORR catalytic activity. The formation of C-O-P bonds improves ORR activity, whereas C-P bonds play an adverse role in stabilizing the key intermediates during the ORR owing to the distorted graphitic structure, as confirmed by the work function value. |
description.department | [sun, xiaoyan ; xu, junyuan ; ding, yuxiao ; zhang, bingsen ; feng, zhenbao ; su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china |
Keyword | Doping Electrocatalysis Onion-like Carbon Oxygen Reduction Phosphorus |
Funding Organization | Ministry of Science and Technology (MOST) [2011CBA00504]; National Natural Science Foundation of China (NSFC) [21133010, 21103203, 51221264, 21261160487, 21203215]; "Strategic Priority Research Program" of the Chinese Academy of Sciences [XDA09030103] |
Indexed By | sci |
Language | 英语 |
WOS ID | WOS:000360915800009 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/75188 |
Collection | 中国科学院金属研究所 |
Corresponding Author | dssu@imr.ac.cn |
Recommended Citation GB/T 7714 | Sun, Xiaoyan,Xu, Junyuan,Ding, Yuxiao,et al. The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction[J]. CHEMSUSCHEM,2015,8(17):2872-2876. |
APA | Sun, Xiaoyan.,Xu, Junyuan.,Ding, Yuxiao.,Zhang, Bingsen.,Feng, Zhenbao.,...&dssu@imr.ac.cn.(2015).The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction.CHEMSUSCHEM,8(17),2872-2876. |
MLA | Sun, Xiaoyan,et al."The Effect of Different Phosphorus Chemical States on an Onion-like Carbon Surface for the Oxygen Reduction Reaction".CHEMSUSCHEM 8.17(2015):2872-2876. |
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