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Triazine-polycarboxylic acid complexes: synthesis, structure and photocatalytic activity
Wang, Zhi Nan; Wang, Xuan; Wei, Si Yue; Wang, Ji Xiao; Bai, Feng Ying; Xing, Yong Heng; Sun, Li Xian; xingyongheng2000@163.com
2015
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume39Issue:5Pages:4168-4177
AbstractFour novel transition metal complexes, [Zn-2(Bpz*eaT)(2)(HBTC)(2)]center dot(CH3OH)(3) (1), [Co(Bpz*eaT)(HBTC)]center dot(CH3CH2OH)(0.5)center dot(H2O)(0.5) (2), [Zn(Bpz*eaT)(H(2)BTA)(pz*H)] (3) and [Cu-4(Mpz*T-O-2)(4)(BTA)(H2O)(8)]center dot 4H(2)O (4) (Bpz*eaT, 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-diethylamino-1,3,5-triazine; Mpz*T-O-2, 6-(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazine-2,4(1H, 3H)-dione; pz*H, 3,5-dimethyl-1H-pyrazole; H3BTC, benzene-1,3,5-tricarboxylic acid; and H(4)BTA, 1,2,4,5-benzenetetracarboxylic acid), were synthesized by the reaction of metal salts (ZnSO4 center dot 7H(2)O, CoCl2 center dot 6H(2)O or CuCl2 center dot 2H(2)O), pincer N-heterocyclic triazine derivatives and aromatic polycarboxylate ligands. All the complexes were characterized by elemental analysis, IR spectroscopy, UV-vis spectroscopy, thermal gravimetric analysis and single-crystal X-ray diffraction. Structural analysis reveals that complexes 1 and 2 are 2-D layers and complex 4 is a 3-D network structure with hydrogen bonding. In addition, the photocatalytic performances of complexes 1-4 were studied under UV irradiation at room temperature and their photocatalytic activity was also discussed. The result showed that complex 1 possessed higher photocatalytic activity.
description.department[wang, zhi nan ; wang, xuan ; wei, si yue ; wang, ji xiao ; xing, yong heng] liaoning normal univ, coll chem & chem engn, dalian 116029, peoples r china ; [wang, xuan] chinese acad sci, inst met res, lab corros & protect, shenyang 110016, peoples r china ; [bai, feng ying] liaoning normal univ, coll life sci, dalian 116029, peoples r china ; [sun, li xian] guilin univ elect technol, guangxi key lab informat mat, guilin 541004, peoples r china
Funding OrganizationNational Natural Science Foundation of China [21071071, 21371086]; Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, P. R. China [1210908-06-K]; Commonwealth Research Foundation of Liaoning province in China [2014003019]
Indexed Bysci
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/75223
Collection中国科学院金属研究所
Corresponding Authorxingyongheng2000@163.com
Recommended Citation
GB/T 7714
Wang, Zhi Nan,Wang, Xuan,Wei, Si Yue,et al. Triazine-polycarboxylic acid complexes: synthesis, structure and photocatalytic activity[J]. NEW JOURNAL OF CHEMISTRY,2015,39(5):4168-4177.
APA Wang, Zhi Nan.,Wang, Xuan.,Wei, Si Yue.,Wang, Ji Xiao.,Bai, Feng Ying.,...&xingyongheng2000@163.com.(2015).Triazine-polycarboxylic acid complexes: synthesis, structure and photocatalytic activity.NEW JOURNAL OF CHEMISTRY,39(5),4168-4177.
MLA Wang, Zhi Nan,et al."Triazine-polycarboxylic acid complexes: synthesis, structure and photocatalytic activity".NEW JOURNAL OF CHEMISTRY 39.5(2015):4168-4177.
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