Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)@UiO-66(Zr) Nanocrystals

IMR OpenIR

	Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)@UiO-66(Zr) Nanocrystals
	Ren, Jianwei; Langmi, Henrietta W.; Musyoka, Nicholas M.; Mathe, Mkhulu; Kang, Xiangdong; Liao, Shijun; jren@csir.co.za
	2015
发表期刊	MATERIALS TODAY-PROCEEDINGS
ISSN	2214-7853
卷号	2 期号:7 页码:3964-3972
摘要	In this work, the existence of structural defects in core-shell MIL-101(Cr)@ UiO-66(Zr) and pure UiO-66(Zr) were proposed. It was found that longer synthesis time leads to larger crystals, which are however not perfect as they morphologically appear to be. During the synthesis, the 1,4-benzenedicarboxylic acid (BDC) linker and modulator (HCOOH) may play competitive roles. The modulator employed does not only modulate the crystal growth, but also contributes in the formation of the MOF framework and promotes defects. Although structural defects would facilitate hydrogen storage in MOF structures, they need to be tuned to an optimum level for hydrogen adsorption purpose. (C) 2015 Elsevier Ltd. All rights reserved.
部门归属	[ren, jianwei ; langmi, henrietta w. ; musyoka, nicholas m. ; mathe, mkhulu] council sci & ind res csir, hysa infrastruct ctr competence mat sci & mfg, za-0001 pretoria, south africa ; [kang, xiangdong] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china ; [liao, shijun] s china univ technol, sch chem & chem engn, guangzhou 510640, guangdong, peoples r china
关键词	Structural Defects Metal-organic Frameworks Modulated Synthesis Hydrogen Storage
收录类别	sci
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/75225
专题	中国科学院金属研究所
通讯作者	jren@csir.co.za
推荐引用方式 GB/T 7714	Ren, Jianwei,Langmi, Henrietta W.,Musyoka, Nicholas M.,et al. Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)@UiO-66(Zr) Nanocrystals[J]. MATERIALS TODAY-PROCEEDINGS,2015,2(7):3964-3972.
APA	Ren, Jianwei.,Langmi, Henrietta W..,Musyoka, Nicholas M..,Mathe, Mkhulu.,Kang, Xiangdong.,...&jren@csir.co.za.(2015).Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)@UiO-66(Zr) Nanocrystals.MATERIALS TODAY-PROCEEDINGS,2(7),3964-3972.
MLA	Ren, Jianwei,et al."Tuning Defects to Facilitate Hydrogen Storage in Core-shell MIL-101(Cr)@UiO-66(Zr) Nanocrystals".MATERIALS TODAY-PROCEEDINGS 2.7(2015):3964-3972.