| The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity | |
| Sun, XiaoYing; Li, Bo; Su, DangSheng; Li, B; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, ShenYang Natl Lab Mat Sci, WenHua Rd 72, Shenyang 110016, Peoples R China. | |
| 2016-06-06 | |
| Source Publication | CHEMISTRY-AN ASIAN JOURNAL
 |
| ISSN | 1861-4728 |
| Volume | 11Issue:11Pages:1668-1671 |
| Abstract | It is believed that the oxygen groups on the carbon catalysts are responsible for the observed reactivity for C-H bond activations. On the other hand, the oxygen groups also reduce the aromaticity of the host. The loss of the aromaticity increases reactivities of the carbon atoms and they become the active sites for the C-H bond activation. The newly identified C-C site exhibits the comparable catalytic performance in the oxidative dehydrogenation (ODH) of propane compared with the conventional oxygen groups like quinone and ketone. A series of calculations indicate that the aromaticity might be a useful descriptor for the carbon catalysts. |
| description.department | [sun, xiaoying] shenyang normal univ, inst catalysis energy & environm, shenyang 110034, peoples r china ; [li, bo ; su, dangsheng] chinese acad sci, inst met res, shenyang natl lab mat sci, wenhua rd 72, shenyang 110016, peoples r china |
| Keyword | Aromaticity Carbon Catalyst Dehydrogenation Heterogeneous Catalysis Nanocatalysis |
| Subject Area | Chemistry |
| Funding Organization | NSFC of China [21573255, 21133010, 51221264]; Chinese Academy of Sciences [XDA09030103]; Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund; Institute of Metal Research [Y3NBA211A1] |
| Indexed By | sci |
| Language | 英语 |
| WOS ID | WOS:000379519100004 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/75835 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Li, B; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, ShenYang Natl Lab Mat Sci, WenHua Rd 72, Shenyang 110016, Peoples R China. |
| Recommended Citation GB/T 7714 | Sun, XiaoYing,Li, Bo,Su, DangSheng,et al. The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(11):1668-1671. |
| APA | Sun, XiaoYing,Li, Bo,Su, DangSheng,Li, B,&Su, DS .(2016).The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity.CHEMISTRY-AN ASIAN JOURNAL,11(11),1668-1671. |
| MLA | Sun, XiaoYing,et al."The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity".CHEMISTRY-AN ASIAN JOURNAL 11.11(2016):1668-1671. |
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