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The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity
Sun, XiaoYing; Li, Bo; Su, DangSheng; Li, B; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, ShenYang Natl Lab Mat Sci, WenHua Rd 72, Shenyang 110016, Peoples R China.
2016-06-06
Source PublicationCHEMISTRY-AN ASIAN JOURNAL
ISSN1861-4728
Volume11Issue:11Pages:1668-1671
AbstractIt is believed that the oxygen groups on the carbon catalysts are responsible for the observed reactivity for C-H bond activations. On the other hand, the oxygen groups also reduce the aromaticity of the host. The loss of the aromaticity increases reactivities of the carbon atoms and they become the active sites for the C-H bond activation. The newly identified C-C site exhibits the comparable catalytic performance in the oxidative dehydrogenation (ODH) of propane compared with the conventional oxygen groups like quinone and ketone. A series of calculations indicate that the aromaticity might be a useful descriptor for the carbon catalysts.
description.department[sun, xiaoying] shenyang normal univ, inst catalysis energy & environm, shenyang 110034, peoples r china ; [li, bo ; su, dangsheng] chinese acad sci, inst met res, shenyang natl lab mat sci, wenhua rd 72, shenyang 110016, peoples r china
KeywordAromaticity Carbon Catalyst Dehydrogenation Heterogeneous Catalysis Nanocatalysis
Subject AreaChemistry
Funding OrganizationNSFC of China [21573255, 21133010, 51221264]; Chinese Academy of Sciences [XDA09030103]; Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund; Institute of Metal Research [Y3NBA211A1]
Indexed Bysci
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/75835
Collection中国科学院金属研究所
Corresponding AuthorLi, B; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, ShenYang Natl Lab Mat Sci, WenHua Rd 72, Shenyang 110016, Peoples R China.
Recommended Citation
GB/T 7714
Sun, XiaoYing,Li, Bo,Su, DangSheng,et al. The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(11):1668-1671.
APA Sun, XiaoYing,Li, Bo,Su, DangSheng,Li, B,&Su, DS .(2016).The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity.CHEMISTRY-AN ASIAN JOURNAL,11(11),1668-1671.
MLA Sun, XiaoYing,et al."The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity".CHEMISTRY-AN ASIAN JOURNAL 11.11(2016):1668-1671.
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