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The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity
Sun, XiaoYing; Li, Bo; Su, DangSheng; Li, B; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, ShenYang Natl Lab Mat Sci, WenHua Rd 72, Shenyang 110016, Peoples R China.
2016-06-06
发表期刊CHEMISTRY-AN ASIAN JOURNAL
ISSN1861-4728
卷号11期号:11页码:1668-1671
摘要It is believed that the oxygen groups on the carbon catalysts are responsible for the observed reactivity for C-H bond activations. On the other hand, the oxygen groups also reduce the aromaticity of the host. The loss of the aromaticity increases reactivities of the carbon atoms and they become the active sites for the C-H bond activation. The newly identified C-C site exhibits the comparable catalytic performance in the oxidative dehydrogenation (ODH) of propane compared with the conventional oxygen groups like quinone and ketone. A series of calculations indicate that the aromaticity might be a useful descriptor for the carbon catalysts.
部门归属[sun, xiaoying] shenyang normal univ, inst catalysis energy & environm, shenyang 110034, peoples r china ; [li, bo ; su, dangsheng] chinese acad sci, inst met res, shenyang natl lab mat sci, wenhua rd 72, shenyang 110016, peoples r china
关键词Aromaticity Carbon Catalyst Dehydrogenation Heterogeneous Catalysis Nanocatalysis
学科领域Chemistry
资助者NSFC of China [21573255, 21133010, 51221264]; Chinese Academy of Sciences [XDA09030103]; Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund; Institute of Metal Research [Y3NBA211A1]
收录类别sci
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/75835
专题中国科学院金属研究所
通讯作者Li, B; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, ShenYang Natl Lab Mat Sci, WenHua Rd 72, Shenyang 110016, Peoples R China.
推荐引用方式
GB/T 7714
Sun, XiaoYing,Li, Bo,Su, DangSheng,et al. The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity[J]. CHEMISTRY-AN ASIAN JOURNAL,2016,11(11):1668-1671.
APA Sun, XiaoYing,Li, Bo,Su, DangSheng,Li, B,&Su, DS .(2016).The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity.CHEMISTRY-AN ASIAN JOURNAL,11(11),1668-1671.
MLA Sun, XiaoYing,et al."The Unexpected Reactivity of the Carbon Sites on the Nanostructured Carbon Catalysts towards the C-H Bond Activation from the Analysis of the Aromaticity".CHEMISTRY-AN ASIAN JOURNAL 11.11(2016):1668-1671.
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