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Electrochemical behavior of B(III) on a molybdenum electrode in NaCl-KCl eutectic molten salt
Wang, Qian; Wang, Yan Li; Liu, Hui Jun; Zeng, Chao Liu; Liu, HJ (reprint author), Chinese Acad Sci, Inst Met Res, Lab Corros & Protect, Shenyang 110016, Peoples R China.
2016
Source PublicationRSC ADVANCES
ISSN2046-2069
Volume6Issue:61Pages:55953-55960
AbstractThe electrochemical behavior of B(III) on a molybdenum electrode in NaCl-KCl-KBF4 molten salt at 1023 K is investigated and the diffusion coefficients of B(III) are calculated by cyclic voltammetry, square wave voltammetry and chronopotentiometry, respectively. The results show that the reduction of B(III) to B(0) is a diffusion-controlled single-step three-electron transfer reaction and the diffusion coefficient of B(III) is calculated to be 4.3 +/- 0.4 x 10(-5) cm(2) s(-1) at 1023 K by cyclic voltammetry. An individual spheroidal aggregate boron coating is obtained by galvanostatic electrolysis.
description.department[wang, qian ; wang, yan li ; liu, hui jun ; zeng, chao liu] chinese acad sci, inst met res, lab corros & protect, shenyang 110016, peoples r china ; [wang, qian] univ sci & technol china, sch mat sci & technol, hefei 230026, peoples r china
Subject AreaChemistry
Funding OrganizationNational Natural Science Foundation of China [51271190, 51501205]
Indexed Bysci
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/75955
Collection中国科学院金属研究所
Corresponding AuthorLiu, HJ (reprint author), Chinese Acad Sci, Inst Met Res, Lab Corros & Protect, Shenyang 110016, Peoples R China.
Recommended Citation
GB/T 7714
Wang, Qian,Wang, Yan Li,Liu, Hui Jun,et al. Electrochemical behavior of B(III) on a molybdenum electrode in NaCl-KCl eutectic molten salt[J]. RSC ADVANCES,2016,6(61):55953-55960.
APA Wang, Qian,Wang, Yan Li,Liu, Hui Jun,Zeng, Chao Liu,&Liu, HJ .(2016).Electrochemical behavior of B(III) on a molybdenum electrode in NaCl-KCl eutectic molten salt.RSC ADVANCES,6(61),55953-55960.
MLA Wang, Qian,et al."Electrochemical behavior of B(III) on a molybdenum electrode in NaCl-KCl eutectic molten salt".RSC ADVANCES 6.61(2016):55953-55960.
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