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Vapor-Dissociation-Solid Growth of Three-Dimensional Graphite like Capsules with Delicate Morphology and Atomic-level Thickness Control
Jian, X; Chen, GZ; Liu, HY; Mahmood, N; Zhu, SB; Yin, LJ; Tang, H; Lv, WQ; He, WD; Zhang, KHL; Zeng, Q; Li, BH; Li, XS; Zhang, WL; Wang, XL; He, WD (reprint author), Univ Elect Sci & Technol China, Sch Energy Sci & Engn, Ctr Micronano Funct Mat & Devices, Chengdu 611731, Peoples R China.; Wang, XL (reprint author), Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, North Wollongong 2500, Australia.; Zeng, Q (reprint author), China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Peoples R China.; Zhang, WL (reprint author), Univ Elect Sci & Technol China, Inst Microelect & Solid State Elect, State key Lab Elect Thin Films & Integrated Devic, Chengdu 610054, Peoples R China.
2016-09-01
Source PublicationCRYSTAL GROWTH & DESIGN
ISSN1528-7483
Volume16Issue:9Pages:5040-5048
AbstractTwo-dimensional graphene is easy to aggregate and hard to transfer because of the van der Waals forces between graphene layers. The three-dimensional (3D) graphite-like capsules (GCs) disperse well and exhibit robust structural stability and have a potential for promising applications in energy storage, drug delivery, catalyst substrate, etc. Here, we develop a catalytic chemical vapor deposition route for the synthesis of 3D GCs with unprecedented thickness and morphology control. The theoretical results indicate that the strong chemisorption and charge transfer between ZnO and acetylene allow the layer-by-layer formation of GCs that is later confirmed by the experimental data. The 3D GCs are synthesized with thickness control from three atomic layers to similar to 300 atomic layers over various oxides with predesigned shapes of microscale tetrapods, nanospheres, nanorods, nanocubes, etc. In particular, the formation mechanism of GCs is investigated using the ZnO surface as a catalyst through systematically experimental approaches. In addition to the high-quality of 3D GCs, this approach provides an unprecedented facile methodological control of coating/functionalizing carbon over various oxides including ZnO, TiO2, SnO2, BaFe12O19, etc.
description.department[jian, xian ; chen, guozhang ; yin, liangjun ; tang, hui ; lv, weiqiang ; he, weidong ; li, baihai] univ elect sci & technol china, sch energy sci & engn, ctr micronano funct mat & devices, chengdu 611731, peoples r china ; [jian, xian ; mahmood, nasir ; wang, xiaolin] univ wollongong, australian inst innovat mat, inst superconducting & elect mat, north wollongong 2500, australia ; [liu, hongyang] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china ; [zhu, shibu] xian aerosp composites res inst, xian 710025, peoples r china ; [zhang, kelvin h. l.] univ cambridge, dept mat sci & met, 27 charles babbage rd, cambridge cb3 0fs, england ; [zeng, qun] china acad engn phys, inst chem mat, mianyang 621900, peoples r china ; [li, xuesong ; zhang, wanli] univ elect sci & technol china, inst microelect & solid state elect, state key lab elect thin films & integrated devic, chengdu 610054, peoples r china
Subject AreaChemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary
Funding OrganizationNational Natural Science Foundation of China [51402040]; China Postdoctoral Science Foundation [2015M582539]; Science and Technology Support Program of Sichuan Province [2016RZ0054]; Open Foundation of State Key Laboratory of Electronic Thin Films and Integrated Devices [KFJJ201411]; National Hi-Tech Research and Development Program (863 Program) of China [2015AA034202]; Automotive CRC, Common Wealth of Australia [1-108]
Indexed Bysci
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/76285
Collection中国科学院金属研究所
Corresponding AuthorHe, WD (reprint author), Univ Elect Sci & Technol China, Sch Energy Sci & Engn, Ctr Micronano Funct Mat & Devices, Chengdu 611731, Peoples R China.; Wang, XL (reprint author), Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, North Wollongong 2500, Australia.; Zeng, Q (reprint author), China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Peoples R China.; Zhang, WL (reprint author), Univ Elect Sci & Technol China, Inst Microelect & Solid State Elect, State key Lab Elect Thin Films & Integrated Devic, Chengdu 610054, Peoples R China.
Recommended Citation
GB/T 7714
Jian, X,Chen, GZ,Liu, HY,et al. Vapor-Dissociation-Solid Growth of Three-Dimensional Graphite like Capsules with Delicate Morphology and Atomic-level Thickness Control[J]. CRYSTAL GROWTH & DESIGN,2016,16(9):5040-5048.
APA Jian, X.,Chen, GZ.,Liu, HY.,Mahmood, N.,Zhu, SB.,...&Zhang, WL .(2016).Vapor-Dissociation-Solid Growth of Three-Dimensional Graphite like Capsules with Delicate Morphology and Atomic-level Thickness Control.CRYSTAL GROWTH & DESIGN,16(9),5040-5048.
MLA Jian, X,et al."Vapor-Dissociation-Solid Growth of Three-Dimensional Graphite like Capsules with Delicate Morphology and Atomic-level Thickness Control".CRYSTAL GROWTH & DESIGN 16.9(2016):5040-5048.
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