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Rapidly Releasing over 9 wt % of H-2 from NH3BH3-Mg or NH3BH3-MgH2 Composites around 85 degrees C
Luo, JH; Kang, XD; Chen, CG; Song, JF; Luo, DL; Wang, P; Luo, JH (reprint author), China Acad Engn Phys, Inst Mat, Jiangyou 621908, Sichuan, Peoples R China.; Wang, P (reprint author), South China Univ Technol, Key Lab Adv Energy Storage Mat Guangdong Prov, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China.
2016-08-25
发表期刊JOURNAL OF PHYSICAL CHEMISTRY C
ISSN1932-7447
卷号120期号:33页码:18386-18393
摘要It is ideal that the hydrogen storage materials for vehicular applications can desorb substantial amounts of hydrogen below 85 degrees C, the operating temperature of polymer electrolyte membrane (PEM) fuel cells. Ammonia borane (NH3BH3, AB for short), because of its intriguingly high hydrogen density (i.e., 19.6 wt %) and moderate thermal stability, is widely regarded as a promising on-board hydrogen storage medium. However, at this temperature, both its dehydrogenation kinetics and deliverable H-capacity are far from meeting the requirements for practical applications. Here, we report that the Mg- or MgH2-modified AB can deliver over 9 wt % of H-2 within 1.5 h at approximately 85 degrees C. Such pronounced dehydrogenation properties are found to be enabled by the combination of three factors, including partial phase transition of normal AB to its mobile phase AB* in the starting material, adequate sample thermal conductivity, and sufficiently intensive external energy input. A further mechanistic study indicates that the dehydrogenation of the AB-Mg or AB-MgH2 sample should likely involve a three-step mechanism, with the formation of a metastable or even unstable magnesium amidoborane phase being a central event.
部门归属[luo, junhong ; chen, changan ; song, jiangfeng ; luo, deli] china acad engn phys, inst mat, jiangyou 621908, sichuan, peoples r china ; [wang, ping] south china univ technol, key lab adv energy storage mat guangdong prov, sch mat sci & engn, guangzhou 510641, guangdong, peoples r china ; [kang, xiangdong] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china ; [luo, junhong] sichuan juneng nucl technol engn co ltd, jiangyou 621700, sichuan, peoples r china
学科领域Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
资助者Sichuan Youth Science & Technology Foundation [2014JQ0060]; National Outstanding Youth Science Foundation of China [51125003]
收录类别sci
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/76300
专题中国科学院金属研究所
通讯作者Luo, JH (reprint author), China Acad Engn Phys, Inst Mat, Jiangyou 621908, Sichuan, Peoples R China.; Wang, P (reprint author), South China Univ Technol, Key Lab Adv Energy Storage Mat Guangdong Prov, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China.
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GB/T 7714
Luo, JH,Kang, XD,Chen, CG,et al. Rapidly Releasing over 9 wt % of H-2 from NH3BH3-Mg or NH3BH3-MgH2 Composites around 85 degrees C[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2016,120(33):18386-18393.
APA Luo, JH.,Kang, XD.,Chen, CG.,Song, JF.,Luo, DL.,...&Wang, P .(2016).Rapidly Releasing over 9 wt % of H-2 from NH3BH3-Mg or NH3BH3-MgH2 Composites around 85 degrees C.JOURNAL OF PHYSICAL CHEMISTRY C,120(33),18386-18393.
MLA Luo, JH,et al."Rapidly Releasing over 9 wt % of H-2 from NH3BH3-Mg or NH3BH3-MgH2 Composites around 85 degrees C".JOURNAL OF PHYSICAL CHEMISTRY C 120.33(2016):18386-18393.
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