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Graphene oxide wrapped Fe2O3 as a durable anode material for high-performance lithium-ion batteries
Li, Henan; Zhu, Xiaofei; Sitinamaluwa, Hansinee; Wasalathilake, Kimal; Xu, Li; Zhang, Shanqing; Yan, Cheng; Li, HN (reprint author), Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China.; Yan, C (reprint author), QUT, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia.
2017-08-15
发表期刊JOURNAL OF ALLOYS AND COMPOUNDS
ISSN0925-8388
卷号714页码:425-432
摘要Ferric oxide has demonstrated as a promising anode candidate for lithium ion batteries ( LIBs) due to large charge storage capacity, but its high cost, low Coulombic efficiency, and unstable solid-electrolyte interphase remain to be a technical challenge. Here, we report a flexible interleaved hybrid in which Fe2O3 nanoparticles were encapsulated by graphene oxide layers (Fe2O3/GO) using facile freeze-drying approach as anode for LIBs. Within this flexible interleaved structure, GO layers act as flexible but mechanically strong buffer to accommodate volume expansion and reduce associated stress in Fe2O3 nanoparticles, thereby maintaining mechanical integrity and increasing the cycling life of batteries. With the synergistic effects from Fe2O3 and GO, this hybrid not only promotes fast mass transfer and shortens the diffusion path of the Li ions but also forms a stable solid electrolyte interface, contributing improved Coulombic efficiency in the first few cycles. The Fe2O3/GO hybrid as anode for LIBs exhibited a reversible specific capacity of ca. 890 mAh g(-1) after 50 cycles at 1 C (1005 mA g(-1)) and 405 mAh g(-1) after 1000 cycles at 10 C rate. Furthermore, a full-cell battery with a LiFePO4 cathode also showed high Coulombic efficiency and good capacity retention capability. Mechanical properties and impedance spectroscopy tests were performed to confirm the mechanism in superior rate and electrochemical stability. The conclusions are considered to be very useful for design of Li batteries with improved mechanical performance. (C) 2017 Elsevier B.V. All rights reserved.; Ferric oxide has demonstrated as a promising anode candidate for lithium ion batteries ( LIBs) due to large charge storage capacity, but its high cost, low Coulombic efficiency, and unstable solid-electrolyte interphase remain to be a technical challenge. Here, we report a flexible interleaved hybrid in which Fe2O3 nanoparticles were encapsulated by graphene oxide layers (Fe2O3/GO) using facile freeze-drying approach as anode for LIBs. Within this flexible interleaved structure, GO layers act as flexible but mechanically strong buffer to accommodate volume expansion and reduce associated stress in Fe2O3 nanoparticles, thereby maintaining mechanical integrity and increasing the cycling life of batteries. With the synergistic effects from Fe2O3 and GO, this hybrid not only promotes fast mass transfer and shortens the diffusion path of the Li ions but also forms a stable solid electrolyte interface, contributing improved Coulombic efficiency in the first few cycles. The Fe2O3/GO hybrid as anode for LIBs exhibited a reversible specific capacity of ca. 890 mAh g(-1) after 50 cycles at 1 C (1005 mA g(-1)) and 405 mAh g(-1) after 1000 cycles at 10 C rate. Furthermore, a full-cell battery with a LiFePO4 cathode also showed high Coulombic efficiency and good capacity retention capability. Mechanical properties and impedance spectroscopy tests were performed to confirm the mechanism in superior rate and electrochemical stability. The conclusions are considered to be very useful for design of Li batteries with improved mechanical performance. (C) 2017 Elsevier B.V. All rights reserved.
部门归属[li, henan ; xu, li] jiangsu univ, sch chem & chem engn, zhenjiang 212013, peoples r china ; [li, henan ; zhu, xiaofei ; sitinamaluwa, hansinee ; wasalathilake, kimal ; yan, cheng] qut, sch chem phys & mech engn, brisbane, qld 4001, australia ; [xu, li ; zhang, shanqing] griffith univ, ctr clean environm & energy, environm futures res inst, gold coast campus, southport, qld 4222, australia ; [xu, li ; zhang, shanqing] griffith univ, griffith sch environm, gold coast campus, southport, qld 4222, australia ; [zhu, xiaofei] chinese acad sci, imr, shenyang 110016, peoples r china
关键词Fe2o3 Graphene Oxide Lithium-ion Batteries Mechanical Properties
学科领域Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
资助者Australian Research Council [DP150101717]; National Natural Science Foundation of China [21506081]
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/78022
专题中国科学院金属研究所
通讯作者Li, HN (reprint author), Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China.; Yan, C (reprint author), QUT, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia.
推荐引用方式
GB/T 7714
Li, Henan,Zhu, Xiaofei,Sitinamaluwa, Hansinee,et al. Graphene oxide wrapped Fe2O3 as a durable anode material for high-performance lithium-ion batteries[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2017,714:425-432.
APA Li, Henan.,Zhu, Xiaofei.,Sitinamaluwa, Hansinee.,Wasalathilake, Kimal.,Xu, Li.,...&Yan, C .(2017).Graphene oxide wrapped Fe2O3 as a durable anode material for high-performance lithium-ion batteries.JOURNAL OF ALLOYS AND COMPOUNDS,714,425-432.
MLA Li, Henan,et al."Graphene oxide wrapped Fe2O3 as a durable anode material for high-performance lithium-ion batteries".JOURNAL OF ALLOYS AND COMPOUNDS 714(2017):425-432.
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