Atmospheric Corrosion of Copper Exposed in a Simulated Coastal-Industrial Atmosphere | |
Pan, Chen; Ly, Wangyan; Wang, Zhenyao; Su, Wei; Wang, Chuan; Liu, Shinian; Wang, ZY (reprint author), Chinese Acad Sci, Inst Met Res, Environm Corros Ctr, Shenyang 110016, Liaoning, Peoples R China. | |
2017-06-01 | |
发表期刊 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
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ISSN | 1005-0302 |
卷号 | 33期号:6页码:587-595 |
摘要 | The corrosion behavior of copper exposed in a simulated coastal-industrial atmosphere has been investigated using weight loss measurement, scanning electron microscopy, X-ray diffraction, potentiodynamic polarization and in-situ electrochemical impedance spectroscopy (EIS) with micro-distance electrodes. The results show that corrosion kinetics follows the empirical equation D = At-n. The main corrosion products are composed of Cu2O, Cu2Cl(OH)(3) and Cu4Cl2(OH)(6). A two-layer structure comprising a loose outer layer and a compact inner layer forms the corrosion products during corrosion process. SO2 has been found to promote the formation of Cu4Cl2(OH)(6). (C) 2016 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.; The corrosion behavior of copper exposed in a simulated coastal-industrial atmosphere has been investigated using weight loss measurement, scanning electron microscopy, X-ray diffraction, potentiodynamic polarization and in-situ electrochemical impedance spectroscopy (EIS) with micro-distance electrodes. The results show that corrosion kinetics follows the empirical equation D = At-n. The main corrosion products are composed of Cu2O, Cu2Cl(OH)(3) and Cu4Cl2(OH)(6). A two-layer structure comprising a loose outer layer and a compact inner layer forms the corrosion products during corrosion process. SO2 has been found to promote the formation of Cu4Cl2(OH)(6). (C) 2016 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. |
部门归属 | [pan, chen ; wang, zhenyao ; wang, chuan] chinese acad sci, inst met res, environm corros ctr, shenyang 110016, liaoning, peoples r china ; [ly, wangyan ; su, wei ; liu, shinian] guangdong power grid corp, elect power res inst, guangzhou 510080, guangdong, peoples r china |
关键词 | Copper Atmospheric Corrosion Sem Eis |
学科领域 | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
资助者 | Technology Projects from China Southern Power Grid [K-GD2014-0532]; National Natural Science Foundation of China [51131007, 51401222] |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000406151300012 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/78091 |
专题 | 中国科学院金属研究所 |
通讯作者 | Wang, ZY (reprint author), Chinese Acad Sci, Inst Met Res, Environm Corros Ctr, Shenyang 110016, Liaoning, Peoples R China. |
推荐引用方式 GB/T 7714 | Pan, Chen,Ly, Wangyan,Wang, Zhenyao,et al. Atmospheric Corrosion of Copper Exposed in a Simulated Coastal-Industrial Atmosphere[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2017,33(6):587-595. |
APA | Pan, Chen.,Ly, Wangyan.,Wang, Zhenyao.,Su, Wei.,Wang, Chuan.,...&Wang, ZY .(2017).Atmospheric Corrosion of Copper Exposed in a Simulated Coastal-Industrial Atmosphere.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,33(6),587-595. |
MLA | Pan, Chen,et al."Atmospheric Corrosion of Copper Exposed in a Simulated Coastal-Industrial Atmosphere".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 33.6(2017):587-595. |
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