Arbitrary-Shaped Graphene-Based Planar Sandwich Supercapacitors on One Substrate with Enhanced Flexibility and Integration

IMR OpenIR

	Arbitrary-Shaped Graphene-Based Planar Sandwich Supercapacitors on One Substrate with Enhanced Flexibility and Integration
	Zheng, Shuanghao; Tang, Xingyan; Wu, Zhong-Shuai; Tan, Yuan-Zhi; Wang, Sen; Sun, Chenglin; Cheng, Hui-Ming; Bao, Xinhe; Wu, ZS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China.
	2017-02-01
发表期刊	ACS NANO
ISSN	1936-0851
卷号	11 期号:2 页码:2171-2179
摘要	The emerging smart power source-unitized electronics represent an utmost innovative paradigm requiring dramatic alteration from materials to device assembly and integration. However, traditional power sources with huge bottlenecks on the design and performance cannot keep pace with the revolutionized progress of shape-confirmable integrated circuits. Here, we demonstrate a versatile printable technology to fabricate arbitrary shaped, printable graphene-based planar sandwich super capacitors based on the layer-structured film of electrochemically exfoliated graphene as two electrodes and nanosized graphene oxide (lateral size of 100 nm) as a separator on one substrate. These monolithic planar supercapacitors not only possess arbitrary shapes, e.g., rectangle, hollow-square, "A" letter, "1" and "2" numbers, circle, and junction-wire shape, but also exhibit outstanding performance (similar to 280 F cm(-3)), excellent flexibility (no capacitance degradation under different bending states), and applicable scalability, which are far beyond those achieved by conventional technologies. More notably, such planar supercapacitors with superior integration can be readily interconnected in parallel and series, without use of metal interconnects and contacts, to modulate the output current and voltage of modular power sources for designable integrated circuits in various shapes and sizes.; The emerging smart power source-unitized electronics represent an utmost innovative paradigm requiring dramatic alteration from materials to device assembly and integration. However, traditional power sources with huge bottlenecks on the design and performance cannot keep pace with the revolutionized progress of shape-confirmable integrated circuits. Here, we demonstrate a versatile printable technology to fabricate arbitrary shaped, printable graphene-based planar sandwich super capacitors based on the layer-structured film of electrochemically exfoliated graphene as two electrodes and nanosized graphene oxide (lateral size of 100 nm) as a separator on one substrate. These monolithic planar supercapacitors not only possess arbitrary shapes, e.g., rectangle, hollow-square, "A" letter, "1" and "2" numbers, circle, and junction-wire shape, but also exhibit outstanding performance (similar to 280 F cm(-3)), excellent flexibility (no capacitance degradation under different bending states), and applicable scalability, which are far beyond those achieved by conventional technologies. More notably, such planar supercapacitors with superior integration can be readily interconnected in parallel and series, without use of metal interconnects and contacts, to modulate the output current and voltage of modular power sources for designable integrated circuits in various shapes and sizes.
部门归属	[zheng, shuanghao ; wu, zhong-shuai ; wang, sen ; sun, chenglin ; bao, xinhe] chinese acad sci, dalian inst chem phys, dalian natl lab clean energy, 457 zhongshan rd, dalian 116023, peoples r china ; [zheng, shuanghao ; bao, xinhe] chinese acad sci, dalian inst chem phys, state key lab catalysis, 457 zhongshan rd, dalian 116023, peoples r china ; [tang, xingyan ; tan, yuan-zhi] xiamen univ, state key lab phys chem solid surfaces, 422 siming south rd, xiamen 361005, peoples r china ; [tang, xingyan ; tan, yuan-zhi] xiamen univ, dept chem, coll chem & chem engn, 422 siming south rd, xiamen 361005, peoples r china ; [zheng, shuanghao ; wang, sen] univ chinese acad sci, 19 a yuquan rd, beijing 100049, peoples r china ; [cheng, hui-ming] chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china ; [cheng, hui-ming] tsinghua univ, tbsi, 1001 xueyuan rd, shenzhen 518055, peoples r china
关键词	Graphene Planar Supercapacitors Arbitrary Shape Printable Flexible Integration
学科领域	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
资助者	Ministry of Science and Technology of China [2016YBF0100100, 2016YFA0200200]; National Natural Science Foundation of China [51572259]; Thousand Youth Talents Plan of China; Natural Science Foundation of Liaoning Province [201602737]; DICP [Y5610121T3]
收录类别	SCI
语种	英语
WOS记录号	WOS:000395357300113
引用统计	被引频次：115[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/78318
专题	中国科学院金属研究所
通讯作者	Wu, ZS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China.
推荐引用方式 GB/T 7714	Zheng, Shuanghao,Tang, Xingyan,Wu, Zhong-Shuai,et al. Arbitrary-Shaped Graphene-Based Planar Sandwich Supercapacitors on One Substrate with Enhanced Flexibility and Integration[J]. ACS NANO,2017,11(2):2171-2179.
APA	Zheng, Shuanghao.,Tang, Xingyan.,Wu, Zhong-Shuai.,Tan, Yuan-Zhi.,Wang, Sen.,...&Wu, ZS .(2017).Arbitrary-Shaped Graphene-Based Planar Sandwich Supercapacitors on One Substrate with Enhanced Flexibility and Integration.ACS NANO,11(2),2171-2179.
MLA	Zheng, Shuanghao,et al."Arbitrary-Shaped Graphene-Based Planar Sandwich Supercapacitors on One Substrate with Enhanced Flexibility and Integration".ACS NANO 11.2(2017):2171-2179.