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A Facile and Efficient Method to Fabricate Highly Selective Nanocarbon Catalysts for Oxidative Dehydrogenation
Zhang, Yajie; Wang, Jia; Rong, Junfeng; Diao, Jiangyong; Zhang, Jiayun; Shi, Chunfeng; Liu, Hongyang; Su, Dangsheng; Liu, HY; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Wenhua Rd 72, Shenyang 110016, Peoples R China.
2017-01-20
发表期刊CHEMSUSCHEM
ISSN1864-5631
卷号10期号:2页码:353-358
摘要Carbon nanotubes (CNTs) were used in oxidative dehydrogenation (ODH) reactions. Quinone groups on the CNT surface were identified as active sites for the dehydrogenation pathway. Liquid-phase oxidation with HNO3 is one way to generate various oxygen functionalities on the CNT surface but it produces a large amount of acid waste, limiting its industrial application. Here, a facile and efficient oxidative method to prepare highly selective CNT catalysts for ODH of n-butane is reported. Magnesium nitrate salts as precursors were used to produce defect-rich CNTs through solid-phase oxidation. Skeleton defects induced on the CNT surface resulted in the selective formation of quinone groups active for the selective dehydrogenation. The as-prepared catalyst exhibited a considerable selectivity (58%) to C-4 olefins, which is superior to that of CNTs oxidized with liquid HNO3. Through the introduction of MgO nanoparticles on the CNT surface, the desorption of alkenes can be accelerated dramatically, thus enhancing the selectivity. This study provides an attractive way to develop new nanocarbon catalysts.; Carbon nanotubes (CNTs) were used in oxidative dehydrogenation (ODH) reactions. Quinone groups on the CNT surface were identified as active sites for the dehydrogenation pathway. Liquid-phase oxidation with HNO3 is one way to generate various oxygen functionalities on the CNT surface but it produces a large amount of acid waste, limiting its industrial application. Here, a facile and efficient oxidative method to prepare highly selective CNT catalysts for ODH of n-butane is reported. Magnesium nitrate salts as precursors were used to produce defect-rich CNTs through solid-phase oxidation. Skeleton defects induced on the CNT surface resulted in the selective formation of quinone groups active for the selective dehydrogenation. The as-prepared catalyst exhibited a considerable selectivity (58%) to C-4 olefins, which is superior to that of CNTs oxidized with liquid HNO3. Through the introduction of MgO nanoparticles on the CNT surface, the desorption of alkenes can be accelerated dramatically, thus enhancing the selectivity. This study provides an attractive way to develop new nanocarbon catalysts.
部门归属[zhang, yajie ; wang, jia ; diao, jiangyong ; zhang, jiayun ; liu, hongyang ; su, dangsheng] chinese acad sci, inst met res, shenyang natl lab mat sci, wenhua rd 72, shenyang 110016, peoples r china ; [zhang, yajie ; zhang, jiayun] univ sci & technol china, sch mat sci & engn, hefei 230026, peoples r china ; [rong, junfeng ; shi, chunfeng] sinopec res inst petr proc, beijing 100083, peoples r china
关键词Basic Promoter Carbon Nanotubes Magnesium Oxide Oxidative Dehydrogenation Solid-phase Oxidation
学科领域Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology
资助者Ministry of Science and Technology (MOST) [2016YFA0204100]; National Natural Science Foundation of China [21573254, 91545110, 21133010, 51221264, 21261160487, 11504386, 21403261]; Youth Innovation Promotion Association (CAS); "Strategic Priority Research Program" of the Chinese Academy of Sciences [XDA09030103]; Sinopec China
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/78333
专题中国科学院金属研究所
通讯作者Liu, HY; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Wenhua Rd 72, Shenyang 110016, Peoples R China.
推荐引用方式
GB/T 7714
Zhang, Yajie,Wang, Jia,Rong, Junfeng,et al. A Facile and Efficient Method to Fabricate Highly Selective Nanocarbon Catalysts for Oxidative Dehydrogenation[J]. CHEMSUSCHEM,2017,10(2):353-358.
APA Zhang, Yajie.,Wang, Jia.,Rong, Junfeng.,Diao, Jiangyong.,Zhang, Jiayun.,...&Su, DS .(2017).A Facile and Efficient Method to Fabricate Highly Selective Nanocarbon Catalysts for Oxidative Dehydrogenation.CHEMSUSCHEM,10(2),353-358.
MLA Zhang, Yajie,et al."A Facile and Efficient Method to Fabricate Highly Selective Nanocarbon Catalysts for Oxidative Dehydrogenation".CHEMSUSCHEM 10.2(2017):353-358.
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