Advanced   Register
IMR OpenIR  > 中国科学院金属研究所  > 期刊论文

题名: Hydrothermal Carbon Enriched with Oxygenated Groups from Bio-mass Glucose as an Efficient Carbocatalyst
作者: Wen, Guodong;  Wang, Bolun;  Wang, Congxin;  Wang, Jia;  Tian, Zhijian;  Schloegl, Robert;  Su, Dang Sheng
发表日期: 2017-1-9
摘要: Metal-free carbocatalysts enriched with specific oxygenated groups with different morphology and size were synthesized from glucose by hydrothermal carbonization, in which cheap and widely available biomass could be converted into functionalized carbon using an environmentally benign process. The hydroxy-and carbonyl-enriched hydrothermal carbon (HTC) could be used in nitrobenzene reduction, and higher conversion was obtained on the sphere morphology with smaller size. In the Beckmann rearrangement of cyclohexanone oxime, carboxyl-enriched HTC exhibited superior performance compared with conventional solid acid (such as HY and HZSM-5), on which the strong acid sites and weak Lewis acid sites lead to high selectivity for the side product. Although the intrinsic acidity of carbon is weak, the carboxyl-enriched carbon was used in weak Bronsted acid-catalyzed reactions, such as the Beckmann rearrangement.
刊名: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Appears in Collections:中国科学院金属研究所_期刊论文

Files in This Item:

There are no files associated with this item.




Recommended Citation:
Wen, Guodong,Wang, Bolun,Wang, Congxin,et al. Hydrothermal Carbon Enriched With Oxygenated Groups From Bio-mass Glucose As An Efficient Carbocatalyst[J]. Angewandte Chemie-international Edition,2017,56(2):600-604.

SCI Citaion Data:
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Wen, Guodong]'s Articles
 [Wang, Bolun]'s Articles
 [Wang, Congxin]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Wen, Guodong]‘s Articles
 [Wang, Bolun]‘s Articles
 [Wang, Congxin]‘s Articles
Scirus search
 Similar articles in Scirus
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Copyright © 2007-2017  中国科学院金属研究所  -Feedback
Powered by CSpace