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题名: Influence of Nitrogen Vacancy Concentration on Mechanical and Electrical Properties of Rocksalt Zirconium Nitride Films
作者: Han, Ke-Chang;  Lin, Guo-Qiang;  Dong, Chuang;  Tai, Kai-Ping;  Jiang, Xin
发表日期: 2017-11-1
摘要: To study the influence of the nitrogen vacancy (V-N) on mechanical and electrical properties of zirconium nitride deeply, ZrNx films with different V-N concentrations were synthesized on the Si (111) substrates by enhanced magnetic filtering arc ion plating. The morphologies, microstructures, residual stresses, compositions, chemical states, mechanical and electrical properties of the as-deposited films were characterized by field-emission scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectrometry, Nanoindenter and Hall effect measurements. The results showed that ZrNx films exhibited rocksalt single-phase structure within a V-N concentration ranging from 26 to 5%. The preferred orientation, thickness, grain size and residual stress of the ZrNx films kept constant at different V-N concentrations. Both the nanohardness and elastic modulus first increased and then decreased with the decrease in V-N concentration, reaching the peaks around 16%. And the electric conductivity of the ZrNx films showed a similar tendency with nanohardness. The underlying atomic-scale mechanisms of V-N concentration-dependent hardness and electric conductivity enhancements were discussed and attributed to the different electronic band structures, rather than conventional meso-scale factors, such as preferred orientation, grain size and residual stress.
刊名: CHINESE ACAD SCIENCES, INST METAL RESEARCH
Appears in Collections:中国科学院金属研究所_期刊论文

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Recommended Citation:
Han, Ke-Chang,Lin, Guo-Qiang,Dong, Chuang,et al. Influence Of Nitrogen Vacancy Concentration On Mechanical And Electrical Properties Of Rocksalt Zirconium Nitride Films[J]. Chinese Acad Sciences, Inst Metal Research,2017,30(11):1100-1108.

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