All-Solid-State Flexible Fiber-Based MXene Supercapacitors

IMR OpenIR

	All-Solid-State Flexible Fiber-Based MXene Supercapacitors
	Hu, Minmin; Li, Zhaojin; Li, Guoxian; Hu, Tao; Zhang, Chao; Wang, Xiaohui; Wang, XH (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China.
	2017-10-01
发表期刊	WILEY
ISSN	2365-709X
卷号	2 期号:10 页码:-
摘要	Flexible fiber-shaped supercapacitors are promising energy-storage devices in wearable smart electronics. Exploring the knittable fiber-type electrode with high capacitance would promote the wide-scale application of such capacitors. Herein, a solution-processed methodology to fabricate all-solid-state, flexible, and fiber-based supercapacitors employing Ti3C2Tx MXene is proposed. Commercially available silver-plated nylon fibers are chosen as fibrous structural support for the first time. Through mildly baking the surfactant-free Ti3C2Tx flakes suspension loaded on the silver-plated nylon fibers, a uniform and adhesive film consisting of Ti3C2Tx nanometer-thick flakes is well established in a parallel manner on the highly conductive fibrous support. It is emphasized that the chemically cross-linked polyvinyl alcohol-H2SO4 hydrogel is served as a solid-state electrolyte that guarantees the structural integrity and mechanical strength of the assembled capacitor. The fabricated capacitor exhibits a high areal capacitance of 328 mF cm(-2) with excellent cyclability and flexibility, capacitance retention remaining at least above 80% under various deformation modes including bending, twisting, and knotting. The device based on the all-solid-state, fiber-type capacitors can drive a light-emitting diode. This work proposes a feasible strategy, offering a platform for rational designs of flexible electronics employing a large family of MXenes and their heterostructures as well.; Flexible fiber-shaped supercapacitors are promising energy-storage devices in wearable smart electronics. Exploring the knittable fiber-type electrode with high capacitance would promote the wide-scale application of such capacitors. Herein, a solution-processed methodology to fabricate all-solid-state, flexible, and fiber-based supercapacitors employing Ti3C2Tx MXene is proposed. Commercially available silver-plated nylon fibers are chosen as fibrous structural support for the first time. Through mildly baking the surfactant-free Ti3C2Tx flakes suspension loaded on the silver-plated nylon fibers, a uniform and adhesive film consisting of Ti3C2Tx nanometer-thick flakes is well established in a parallel manner on the highly conductive fibrous support. It is emphasized that the chemically cross-linked polyvinyl alcohol-H2SO4 hydrogel is served as a solid-state electrolyte that guarantees the structural integrity and mechanical strength of the assembled capacitor. The fabricated capacitor exhibits a high areal capacitance of 328 mF cm(-2) with excellent cyclability and flexibility, capacitance retention remaining at least above 80% under various deformation modes including bending, twisting, and knotting. The device based on the all-solid-state, fiber-type capacitors can drive a light-emitting diode. This work proposes a feasible strategy, offering a platform for rational designs of flexible electronics employing a large family of MXenes and their heterostructures as well.
部门归属	[hu, minmin ; li, zhaojin ; li, guoxian ; hu, tao ; zhang, chao ; wang, xiaohui] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, liaoning, peoples r china ; [hu, minmin] univ sci & technol china, sch mat sci & engn, shenyang 110016, liaoning, peoples r china ; [li, zhaojin ; li, guoxian ; hu, tao] univ chinese acad sci, beijing 100049, peoples r china
关键词	2d Materials All-solid-state Electrolytes Flexibility Mxene Supercapacitors
学科领域	Materials Science, Multidisciplinary
资助者	Youth Innovation Promotion Association, Chinese Academy of Sciences (CAS) [2011152]; Shenyang National Laboratory for Materials Science, Institute of Metal Research, CAS [2017RP06]
收录类别	SCI
语种	英语
WOS记录号	WOS:000412664100014
引用统计	被引频次：176[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/79059
专题	中国科学院金属研究所
通讯作者	Wang, XH (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China.
推荐引用方式 GB/T 7714	Hu, Minmin,Li, Zhaojin,Li, Guoxian,et al. All-Solid-State Flexible Fiber-Based MXene Supercapacitors[J]. WILEY,2017,2(10):-.
APA	Hu, Minmin.,Li, Zhaojin.,Li, Guoxian.,Hu, Tao.,Zhang, Chao.,...&Wang, XH .(2017).All-Solid-State Flexible Fiber-Based MXene Supercapacitors.WILEY,2(10),-.
MLA	Hu, Minmin,et al."All-Solid-State Flexible Fiber-Based MXene Supercapacitors".WILEY 2.10(2017):-.