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Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond
Lin, Yangming; Wu, Kuang-Hsu (Tim); Yu, Linhui; Heumann, Saskia; Su, Dang Sheng; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China.; Su, DS (reprint author), Fritz Haber Inst Max, Dept Inorgan Chem, Planck Soc, Faradayweg 4-6, D-14195 Berlin, Germany.
2017-09-11
发表期刊WILEY-V C H VERLAG GMBH
ISSN1864-5631
卷号10期号:17页码:3497-3505
摘要Selective oxidation of alcohols to aldehydes is widely applicable to the synthesis of various green chemicals. The poor chemoselectivity for complicated primary aldehydes over state-of-the-art metal-free or metal-based catalysts represents a major obstacle for industrial application. Bucky nanodiamond is a potential green catalyst that exhibits excellent chemoselectivity and cycling stability for the selective oxidation of primary alcohols in diverse structures (22examples, including aromatic, substituted aromatic, unsaturated, heterocyclic, and linear chain alcohols) to their corresponding aldehydes. The results are comparable to reported transition-metal catalysts including conventional Pt/C and Ru/C catalysts for certain substrates under solvent-free conditions. The possible activation process of the oxidant and substrates by the surface oxygen groups and defect species are revealed with model catalysts, exsitu electrochemical measurements, and exsitu attenuated total reflectance. The zigzag edges of sp(2) carbon planes are shown to play a key role in these reactions.; Selective oxidation of alcohols to aldehydes is widely applicable to the synthesis of various green chemicals. The poor chemoselectivity for complicated primary aldehydes over state-of-the-art metal-free or metal-based catalysts represents a major obstacle for industrial application. Bucky nanodiamond is a potential green catalyst that exhibits excellent chemoselectivity and cycling stability for the selective oxidation of primary alcohols in diverse structures (22examples, including aromatic, substituted aromatic, unsaturated, heterocyclic, and linear chain alcohols) to their corresponding aldehydes. The results are comparable to reported transition-metal catalysts including conventional Pt/C and Ru/C catalysts for certain substrates under solvent-free conditions. The possible activation process of the oxidant and substrates by the surface oxygen groups and defect species are revealed with model catalysts, exsitu electrochemical measurements, and exsitu attenuated total reflectance. The zigzag edges of sp(2) carbon planes are shown to play a key role in these reactions.
部门归属[lin, yangming ; wu, kuang-hsu (tim) ; su, dang sheng] chinese acad sci, inst met res, 72 wenhua rd, shenyang 110016, liaoning, peoples r china ; [lin, yangming] univ sci & technol china, sch chem & mat sci, hefei 230001, anhui, peoples r china ; [lin, yangming ; heumann, saskia] max planck inst chem energy convers, stiftstr 34-36, d-45470 mulheim, germany ; [yu, linhui] fuzhou univ, res inst photocatalysis, fuzhou 350002, peoples r china ; [su, dang sheng] fritz haber inst max, dept inorgan chem, planck soc, faradayweg 4-6, d-14195 berlin, germany
关键词Alcohols Carbocatalysis Electrochemistry Oxidation Redox Reactions
学科领域Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology
资助者Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09030103]
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/79100
专题中国科学院金属研究所
通讯作者Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China.; Su, DS (reprint author), Fritz Haber Inst Max, Dept Inorgan Chem, Planck Soc, Faradayweg 4-6, D-14195 Berlin, Germany.
推荐引用方式
GB/T 7714
Lin, Yangming,Wu, Kuang-Hsu ,Yu, Linhui,et al. Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond[J]. WILEY-V C H VERLAG GMBH,2017,10(17):3497-3505.
APA Lin, Yangming.,Wu, Kuang-Hsu .,Yu, Linhui.,Heumann, Saskia.,Su, Dang Sheng.,...&Su, DS .(2017).Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond.WILEY-V C H VERLAG GMBH,10(17),3497-3505.
MLA Lin, Yangming,et al."Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond".WILEY-V C H VERLAG GMBH 10.17(2017):3497-3505.
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