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Fabrication of Monodisperse Flower-Like Coordination Polymers (CP) Microparticles by Spray Technique
Li, Wen-Ze; Zhou, Yuan; Liu, Fuchun; Li, Yunong; Xia, Ming-Jian; Han, En-Hou; Wang, Tieqiang; Zhang, Xuemin; Fu, Yu; Li, WZ (reprint author), Shenyang Univ Chem Technol, Dept Appl Chem, Shenyang 110142, Liaoning, Peoples R China.; Fu, Y (reprint author), Northeastern Univ, Coll Sci, Shenyang 110819, Liaoning, Peoples R China.
2017-09-01
发表期刊MDPI AG
ISSN2079-4991
卷号7期号:9页码:-
摘要In this manuscript, we have developed an efficient spraying method to successfully fabricate a series of flower-like coordination polymers (CP) microparticles, including Co/BDC (1,4-benzenedicarboxylate) metal organic frameworks (MOF) and infinite coordination polymers (ICP) microparticles, as well as Ni-Co/BDC MOF and Zn/DOBDC (2,5-dioxido-1,4-benzenedicarboxylate) MOF. The spraying method has shown high efficiency and universality in synthesizing the flower-like CP. The crystalline structure can be adjusted by varying the solvent composition in the spraying process. SEM observation demonstrated the MOF and ICP microparticles possess the similar flower-like structure, which is composed of nanoflakes with smooth surface, and the flower-like microparticles could be monodisperse with as low as 5% polydispersity. Moreover, the fabrication of the flower-like CP microparticles by spraying has a wide operation window, because there is no need to precisely control the experiment conditions, like solvents, concentration, and spray order. Due to the practicality of spray technique, this work would pave the way for the manufacture of the flower-like materials and have great potential in applications of catalysis, sensor, energy storage, and so on.; In this manuscript, we have developed an efficient spraying method to successfully fabricate a series of flower-like coordination polymers (CP) microparticles, including Co/BDC (1,4-benzenedicarboxylate) metal organic frameworks (MOF) and infinite coordination polymers (ICP) microparticles, as well as Ni-Co/BDC MOF and Zn/DOBDC (2,5-dioxido-1,4-benzenedicarboxylate) MOF. The spraying method has shown high efficiency and universality in synthesizing the flower-like CP. The crystalline structure can be adjusted by varying the solvent composition in the spraying process. SEM observation demonstrated the MOF and ICP microparticles possess the similar flower-like structure, which is composed of nanoflakes with smooth surface, and the flower-like microparticles could be monodisperse with as low as 5% polydispersity. Moreover, the fabrication of the flower-like CP microparticles by spraying has a wide operation window, because there is no need to precisely control the experiment conditions, like solvents, concentration, and spray order. Due to the practicality of spray technique, this work would pave the way for the manufacture of the flower-like materials and have great potential in applications of catalysis, sensor, energy storage, and so on.
部门归属[li, wen-ze] shenyang univ chem technol, dept appl chem, shenyang 110142, liaoning, peoples r china ; [zhou, yuan ; li, yunong ; xia, ming-jian ; wang, tieqiang ; zhang, xuemin ; fu, yu] northeastern univ, coll sci, shenyang 110819, liaoning, peoples r china ; [liu, fuchun ; han, en-hou] chinese acad sci, inst met res, key lab nucl mat & safety assessment, shenyang 110016, liaoning, peoples r china
关键词Coordination Polymers Metal-organic Frameworks (Mof) Spray Flower-like Microparticles
学科领域Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
资助者National Natural Science Foundation of China [21404021, 21503037, 51601032]; Doctoral Scientific Research Foundation of Liaoning Province [20141013, 201501149]; Fundamental Research Funds for the Central Universities [N150504004, N150504005, N140502001, N140503001, N160504002]; Project of Liaoning Province Key Laboratory [LZ2016007]; Special Scientific Research on Civil Aircraft [MTE-2016-F-08]; Open Project of the State Key Laboratory of Supramolecular Structure and Materials [sklssm201705]
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/79114
专题中国科学院金属研究所
通讯作者Li, WZ (reprint author), Shenyang Univ Chem Technol, Dept Appl Chem, Shenyang 110142, Liaoning, Peoples R China.; Fu, Y (reprint author), Northeastern Univ, Coll Sci, Shenyang 110819, Liaoning, Peoples R China.
推荐引用方式
GB/T 7714
Li, Wen-Ze,Zhou, Yuan,Liu, Fuchun,et al. Fabrication of Monodisperse Flower-Like Coordination Polymers (CP) Microparticles by Spray Technique[J]. MDPI AG,2017,7(9):-.
APA Li, Wen-Ze.,Zhou, Yuan.,Liu, Fuchun.,Li, Yunong.,Xia, Ming-Jian.,...&Fu, Y .(2017).Fabrication of Monodisperse Flower-Like Coordination Polymers (CP) Microparticles by Spray Technique.MDPI AG,7(9),-.
MLA Li, Wen-Ze,et al."Fabrication of Monodisperse Flower-Like Coordination Polymers (CP) Microparticles by Spray Technique".MDPI AG 7.9(2017):-.
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