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题名: Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes
作者: Gupta, Neeraj;  Khavryuchenko, Oleksiy;  Villa, Alberto;  Su, Dangsheng
发表日期: 2017-8-10
摘要: Nitrogen rich carbon nanotubes have been used as a metal free catalyst for the conversion of glycerol into dihydroxyacetone using tert-butyl hydroperoxide as an oxidant. Pyridine nitrogen groups embedded in a carbon matrix are identified as active sites for the reaction. Computational studies have demonstrated that oxidation of pyridine groups to pyridine oxime followed by hydrogen abstraction from secondary alcohol is likely responsible for the oxidation process.
刊名: WILEY-V C H VERLAG GMBH
Appears in Collections:中国科学院金属研究所_期刊论文

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Recommended Citation:
Gupta, Neeraj,Khavryuchenko, Oleksiy,Villa, Alberto,et al. Metal-free Oxidation Of Glycerol Over Nitrogen-containing Carbon Nanotubes[J]. Wiley-v C H Verlag Gmbh,2017,10(15):3030-3034.

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