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Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes
Gupta, Neeraj; Khavryuchenko, Oleksiy; Villa, Alberto; Su, Dangsheng; Su, DS (reprint author), Chinese Acad Sci, Catalysis Div, IMR Shenyang Natl Lab, Shenyang 110016, Liaoning, Peoples R China.; Villa, A (reprint author), Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy.; Su, DS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China.
2017-08-10
Source PublicationWILEY-V C H VERLAG GMBH
ISSN1864-5631
Volume10Issue:15Pages:3030-3034
AbstractNitrogen rich carbon nanotubes have been used as a metal free catalyst for the conversion of glycerol into dihydroxyacetone using tert-butyl hydroperoxide as an oxidant. Pyridine nitrogen groups embedded in a carbon matrix are identified as active sites for the reaction. Computational studies have demonstrated that oxidation of pyridine groups to pyridine oxime followed by hydrogen abstraction from secondary alcohol is likely responsible for the oxidation process.; Nitrogen rich carbon nanotubes have been used as a metal free catalyst for the conversion of glycerol into dihydroxyacetone using tert-butyl hydroperoxide as an oxidant. Pyridine nitrogen groups embedded in a carbon matrix are identified as active sites for the reaction. Computational studies have demonstrated that oxidation of pyridine groups to pyridine oxime followed by hydrogen abstraction from secondary alcohol is likely responsible for the oxidation process.
description.department[gupta, neeraj ; su, dangsheng] chinese acad sci, catalysis div, imr shenyang natl lab, shenyang 110016, liaoning, peoples r china ; [khavryuchenko, oleksiy] tmm llc, res & dev dept, volodymyrska str 49a, kiev, ukraine ; [villa, alberto] univ milan, dipartimento chim, via golgi 19, i-20133 milan, italy ; [su, dangsheng] chinese acad sci, dalian inst chem phys, dalian, peoples r china
KeywordBiomass Conversion Carbon Nanotubes Glycerol Metal-free Oxidation Ncnts
Subject AreaChemistry, Multidisciplinary ; Green & Sustainable Science & Technology
Funding OrganizationChinese Academy of Sciences [2014FFGB0006]; Universita degli Studi di Milano, "Piano di sviluppo d'ateneo, Linea 2 Azione A"
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/79153
Collection中国科学院金属研究所
Corresponding AuthorSu, DS (reprint author), Chinese Acad Sci, Catalysis Div, IMR Shenyang Natl Lab, Shenyang 110016, Liaoning, Peoples R China.; Villa, A (reprint author), Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy.; Su, DS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China.
Recommended Citation
GB/T 7714
Gupta, Neeraj,Khavryuchenko, Oleksiy,Villa, Alberto,et al. Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes[J]. WILEY-V C H VERLAG GMBH,2017,10(15):3030-3034.
APA Gupta, Neeraj.,Khavryuchenko, Oleksiy.,Villa, Alberto.,Su, Dangsheng.,Su, DS .,...&Su, DS .(2017).Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes.WILEY-V C H VERLAG GMBH,10(15),3030-3034.
MLA Gupta, Neeraj,et al."Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes".WILEY-V C H VERLAG GMBH 10.15(2017):3030-3034.
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