One-Step Device Fabrication of Phosphorene and Graphene Interdigital Micro-dSupercapacitors with High Energy Density

IMR OpenIR

	One-Step Device Fabrication of Phosphorene and Graphene Interdigital Micro-dSupercapacitors with High Energy Density
	Xiao, Han; Wu, Zhong-Shuai; Chen, Long; Zhou, Feng; Zheng, Shuanghao; Ren, Wencai; Cheng, Hui-Ming; Bao, Xinhe; Wu, ZS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China.; Ren, WC (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China.
	2017-07-01
发表期刊	AMER CHEMICAL SOC
ISSN	1936-0851
卷号	11 期号:7 页码:7284-7292
摘要	Rational engineering and simplified fabrication of high-energy micro-supercapacitors (MSCs) using graphene and other 2D nanosheets are of great value for flexible and integrated electronics. Here we develop onestep mask-assisted simplified fabrication of high-energy MSCs (PG-MSCs) based on the interdigital hybrid electrode (PG) patterns of stacking high-quality phosphorene nanosheets and electrochemically exfoliated graphene in ionic liquid electrolyte. The hybrid PG films with interdigital patterns were directly manufactured by layer-by layer deposition of phosphorene and graphene nanosheets with the assistance of a customized interdigital mask, and directly transferred onto a flexible substrate. The resultant patterned PG films present outstanding uniformity, flexibility, conductivity (319 S cm(-1)), and structural integration, which can directly serve as binder- and additive-free flexible electrodes for MSCs. Remarkably, PG-MSCs deliver remarkable energy density of 11.6 mWh cm(-3), outperforming most nanocarbon-based MSCs. Moreover, our PG-MSCs show outstanding flexibility and stable performance with slight capacitance fluctuation even under highly folded states. In addition, our simplified mask-assisted strategy for PG-MSCs is highly flexible for simplified production of parallelly and serially interconnected modular power sources, without need of conventional metal-based interconnects and contacts, for designable integrated circuits with high output current and voltage.; Rational engineering and simplified fabrication of high-energy micro-supercapacitors (MSCs) using graphene and other 2D nanosheets are of great value for flexible and integrated electronics. Here we develop onestep mask-assisted simplified fabrication of high-energy MSCs (PG-MSCs) based on the interdigital hybrid electrode (PG) patterns of stacking high-quality phosphorene nanosheets and electrochemically exfoliated graphene in ionic liquid electrolyte. The hybrid PG films with interdigital patterns were directly manufactured by layer-by layer deposition of phosphorene and graphene nanosheets with the assistance of a customized interdigital mask, and directly transferred onto a flexible substrate. The resultant patterned PG films present outstanding uniformity, flexibility, conductivity (319 S cm(-1)), and structural integration, which can directly serve as binder- and additive-free flexible electrodes for MSCs. Remarkably, PG-MSCs deliver remarkable energy density of 11.6 mWh cm(-3), outperforming most nanocarbon-based MSCs. Moreover, our PG-MSCs show outstanding flexibility and stable performance with slight capacitance fluctuation even under highly folded states. In addition, our simplified mask-assisted strategy for PG-MSCs is highly flexible for simplified production of parallelly and serially interconnected modular power sources, without need of conventional metal-based interconnects and contacts, for designable integrated circuits with high output current and voltage.
部门归属	[xiao, han ; wu, zhong-shuai ; zhou, feng ; zheng, shuanghao ; bao, xinhe] chinese acad sci, dalian inst chem phys, dalian natl lab clean energy, 457 zhongshan rd, dalian 116023, peoples r china ; [chen, long ; ren, wencai ; cheng, hui-ming] chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china ; [chen, long ; zheng, shuanghao] univ chinese acad sci, 19 a yuquan rd, beijing 100049, peoples r china ; [zheng, shuanghao] chinese acad sci, dalian inst chem phys, state key lab catalysis, 457 zhongshan rd, dalian 116023, peoples r china ; [cheng, hui-ming] tsinghua univ, tbsi, 1001 xueyuan rd, shenzhen 518055, peoples r china
关键词	Phosphorene Graphene Micro-supercapacitors Ionic Liquid Energy Storage
学科领域	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
资助者	National Natural Science Foundation of China [51572259, 51325205, 51290273, 51521091]; National Key RAMP;D Program of China [2016YBF0100100, 2016YFA0200101, 2016YFA0200200]; Natural Science Foundation of Liaoning Province [201602737]; Thousand Youth Talents Plan of China, DICP [Y5610121T3]; China Postdoctoral Science Foundation [2016M601348]
收录类别	SCI
语种	英语
WOS记录号	WOS:000406649700077
引用统计	被引频次：298[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/79179
专题	中国科学院金属研究所
通讯作者	Wu, ZS (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China.; Ren, WC (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China.
推荐引用方式 GB/T 7714	Xiao, Han,Wu, Zhong-Shuai,Chen, Long,et al. One-Step Device Fabrication of Phosphorene and Graphene Interdigital Micro-dSupercapacitors with High Energy Density[J]. AMER CHEMICAL SOC,2017,11(7):7284-7292.
APA	Xiao, Han.,Wu, Zhong-Shuai.,Chen, Long.,Zhou, Feng.,Zheng, Shuanghao.,...&Ren, WC .(2017).One-Step Device Fabrication of Phosphorene and Graphene Interdigital Micro-dSupercapacitors with High Energy Density.AMER CHEMICAL SOC,11(7),7284-7292.
MLA	Xiao, Han,et al."One-Step Device Fabrication of Phosphorene and Graphene Interdigital Micro-dSupercapacitors with High Energy Density".AMER CHEMICAL SOC 11.7(2017):7284-7292.