Surface Modification and Electrochemical Lithium Storage Performance of TiO2-Anatase Nanotube Arrays with CuO

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	Surface Modification and Electrochemical Lithium Storage Performance of TiO2-Anatase Nanotube Arrays with CuO
	Yao, YH; Yuan, ZT; Zhang, YN; Yu, XH; Rong, J; Meng, K; Zhan, ZL; Yu, XH (reprint author), Kunming Univ Sci & Technol, Natl Engn Res Ctr Solid Waste Resource, Kunming 650093, Yunnan, Peoples R China.; Yu, XH (reprint author), Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Kunming 650093, Yunnan, Peoples R China.
	2018-04-10
发表期刊	CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN	1001-4861
卷号	34 期号:4 页码:662-668
摘要	Anodic oxidation and hydrothermal method were jointly used to prepare CuO/TiO2 negative material which was synthesized from ethylene glycol, ammonium fluoride, hydrochloric acid, cupric chloride and sodium nitrate. Morphology, element distribution, valence state, microcosmic phase composition of the samples were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD). Furthermore, the electrochemical lithium insertion properties of CuO/TiO2 were tested by the use of battery charge and discharge testing system and electrochemical workstation. The results show that there are particulates arrange the surface of the anatase TiO2 nanotube. The nanometer size was 4 nm x 10 nm. The as prepared CuO/TiO2 displays plummy electric properties of initial discharge and charge capacities of 550 and 490 mAh.g(-1) at the rate of 0.3C. respectively. After 50 cycles the reserve capacities is 320 mAh.g(-1).; Anodic oxidation and hydrothermal method were jointly used to prepare CuO/TiO2 negative material which was synthesized from ethylene glycol, ammonium fluoride, hydrochloric acid, cupric chloride and sodium nitrate. Morphology, element distribution, valence state, microcosmic phase composition of the samples were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD). Furthermore, the electrochemical lithium insertion properties of CuO/TiO2 were tested by the use of battery charge and discharge testing system and electrochemical workstation. The results show that there are particulates arrange the surface of the anatase TiO2 nanotube. The nanometer size was 4 nm x 10 nm. The as prepared CuO/TiO2 displays plummy electric properties of initial discharge and charge capacities of 550 and 490 mAh.g(-1) at the rate of 0.3C. respectively. After 50 cycles the reserve capacities is 320 mAh.g(-1).
部门归属	[yao yu-han ; yu xiao-hua] kunming univ sci & technol, natl engn res ctr solid waste resource, kunming 650093, yunnan, peoples r china ; [yao yu-han ; yuan zhen-tao ; zhang yan-nan ; yu xiao-hua ; rong ju ; meng kun ; zhan zhao-lin] kunming univ sci & technol, fac mat sci & engn, kunming 650093, yunnan, peoples r china ; [rong ju] chinese acad sci, inst met res, shenyang 110016, liaoning, peoples r china
关键词	Battery Anode Materials Li-ion Batteries Nanowire Arrays Reversible Capacity Energy Size Oxidation Tio2 Electrolyte Stability
学科领域	Chemistry, Inorganic & Nuclear
收录类别	SCI
语种	英语
WOS记录号	WOS:000431388400007
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/79371
专题	中国科学院金属研究所
通讯作者	Yu, XH (reprint author), Kunming Univ Sci & Technol, Natl Engn Res Ctr Solid Waste Resource, Kunming 650093, Yunnan, Peoples R China.; Yu, XH (reprint author), Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Kunming 650093, Yunnan, Peoples R China.
推荐引用方式 GB/T 7714	Yao, YH,Yuan, ZT,Zhang, YN,et al. Surface Modification and Electrochemical Lithium Storage Performance of TiO2-Anatase Nanotube Arrays with CuO[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2018,34(4):662-668.
APA	Yao, YH.,Yuan, ZT.,Zhang, YN.,Yu, XH.,Rong, J.,...&Yu, XH .(2018).Surface Modification and Electrochemical Lithium Storage Performance of TiO2-Anatase Nanotube Arrays with CuO.CHINESE JOURNAL OF INORGANIC CHEMISTRY,34(4),662-668.
MLA	Yao, YH,et al."Surface Modification and Electrochemical Lithium Storage Performance of TiO2-Anatase Nanotube Arrays with CuO".CHINESE JOURNAL OF INORGANIC CHEMISTRY 34.4(2018):662-668.