Engineering Gold Nanorod-Copper Sulfide Heterostructures with Enhanced Photothermal Conversion Efficiency and Photostability

IMR OpenIR

	Engineering Gold Nanorod-Copper Sulfide Heterostructures with Enhanced Photothermal Conversion Efficiency and Photostability
	Leng, CB; Zhang, X; Xu, FX; Yuan, Y; Pei, H; Sun, ZH; Li, L; Bao, ZH; Bao, ZH (reprint author), Shenyang Pharmaceut Univ, Sch Pharm, Shenyang 110016, Liaoning, Peoples R China.; Li, L (reprint author), East China Normal Univ, Sch Chem & Mol Engn, Shanghai 200241, Peoples R China.
	2018-03-22
发表期刊	SMALL
ISSN	1613-6810
卷号	14 期号:12 页码:-
摘要	Plasmonic gold nanorods (Au NRs)-copper sulfide heterostructures have recently attracted much attention owing to the synergistically enhanced photothermal properties. However, the facile synthesis and interface tailoring of Au NRs-copper sulfide heterostructures remain a formidable challenge. In this study, the rational design and synthesis of Au NRs-Cu7S4 heterostructures via a one-pot hydrothermal process is reported. Specifically, core-shell and dumbbell-like Au NRs-Cu7S4 heterostructures are obtained with well-controlled interfaces by employing the Au NRs with different aspect ratios. Both core-shell and dumbbell-like Au NRs-Cu7S4 have proven effective as photothermal therapy agents, which offer both high photothermal stability and significant photothermal conversion efficiency up to 62%. The finite-difference time domain simulation results confirm the coupling effect that leads to the enhanced local field as well as the optical absorption at the heterostructure interface. Importantly, these Au NRs-Cu7S4 heterostructures can be compatibly used as an 808 nm laser-driven photothermal therapy agents for the efficient photothermal therapy of cancer cells in vitro. This study will provide new insight into the design of other noble metal-semiconductor heterostructures for a broad range of applications utilizing surface plasmon resonance enhancement phenomena.; Plasmonic gold nanorods (Au NRs)-copper sulfide heterostructures have recently attracted much attention owing to the synergistically enhanced photothermal properties. However, the facile synthesis and interface tailoring of Au NRs-copper sulfide heterostructures remain a formidable challenge. In this study, the rational design and synthesis of Au NRs-Cu7S4 heterostructures via a one-pot hydrothermal process is reported. Specifically, core-shell and dumbbell-like Au NRs-Cu7S4 heterostructures are obtained with well-controlled interfaces by employing the Au NRs with different aspect ratios. Both core-shell and dumbbell-like Au NRs-Cu7S4 have proven effective as photothermal therapy agents, which offer both high photothermal stability and significant photothermal conversion efficiency up to 62%. The finite-difference time domain simulation results confirm the coupling effect that leads to the enhanced local field as well as the optical absorption at the heterostructure interface. Importantly, these Au NRs-Cu7S4 heterostructures can be compatibly used as an 808 nm laser-driven photothermal therapy agents for the efficient photothermal therapy of cancer cells in vitro. This study will provide new insight into the design of other noble metal-semiconductor heterostructures for a broad range of applications utilizing surface plasmon resonance enhancement phenomena.
部门归属	[leng, chunbo ; yuan, yue ; bao, zhihong] shenyang pharmaceut univ, sch pharm, shenyang 110016, liaoning, peoples r china ; [leng, chunbo ; pei, hao ; li, li] east china normal univ, sch chem & mol engn, shanghai 200241, peoples r china ; [zhang, xin ; xu, fanxing] shenyang pharmaceut univ, sch life sci & biopharmaceut, shenyang 110016, liaoning, peoples r china ; [sun, zhenhua] chinese acad sci, inst met res, shenyang 110016, liaoning, peoples r china
关键词	Core-shell Cancer-treatment Nanoparticles Nanocrystals Therapy Oxide Agent Nanomaterials Absorption Electrodes
学科领域	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
资助者	Natural Science Foundation of Liaoning Province of China [201602688]; National Natural Science Foundation of China [21401132, 21505045]; Shanghai Pujiang Program [16PJ1402700, 15PJ1401800]; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University [ZQN2015026]; Research Project of Science and Technology of Department of Education of Liaoning Province [L2014401]
收录类别	SCI
语种	英语
WOS记录号	WOS:000428344300011
引用统计	被引频次：115[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/79421
专题	中国科学院金属研究所
通讯作者	Bao, ZH (reprint author), Shenyang Pharmaceut Univ, Sch Pharm, Shenyang 110016, Liaoning, Peoples R China.; Li, L (reprint author), East China Normal Univ, Sch Chem & Mol Engn, Shanghai 200241, Peoples R China.
推荐引用方式 GB/T 7714	Leng, CB,Zhang, X,Xu, FX,et al. Engineering Gold Nanorod-Copper Sulfide Heterostructures with Enhanced Photothermal Conversion Efficiency and Photostability[J]. SMALL,2018,14(12):-.
APA	Leng, CB.,Zhang, X.,Xu, FX.,Yuan, Y.,Pei, H.,...&Li, L .(2018).Engineering Gold Nanorod-Copper Sulfide Heterostructures with Enhanced Photothermal Conversion Efficiency and Photostability.SMALL,14(12),-.
MLA	Leng, CB,et al."Engineering Gold Nanorod-Copper Sulfide Heterostructures with Enhanced Photothermal Conversion Efficiency and Photostability".SMALL 14.12(2018):-.