Effect of perfluorodecyltrichlorosilane on the surface properties and anti-corrosion behavior of poly(dimethylsiloxane)-ZnO coatings

IMR OpenIR

	Effect of perfluorodecyltrichlorosilane on the surface properties and anti-corrosion behavior of poly(dimethylsiloxane)-ZnO coatings
	Arukalam, IO; Meng, MJ; Xiao, HG; Ma, YT; Oguzie, EE; Li, Y; Li, Y (reprint author), Chinese Acad Sci, Inst Met Res, 62 Wencui Rd, Shenyang 110016, Liaoning, Peoples R China.
	2018-03-01
发表期刊	APPLIED SURFACE SCIENCE
ISSN	0169-4332
卷号	433 页码:1113-1127
摘要	Poly(dimethylsiloxane)-ZnO coatings modified with different amounts of perfluorodecyltrichlorosilane (FDTS) were prepared using sol-gel technique. The results of field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM) examinations showed that the surface structures and roughness of the coatings were respectively influenced by the increasing addition of FDTS. The water contact angle measurements showed maximum value of 130.52 degrees with the 0.10 g FDTS-modified coating sample. The X-ray photoelectron spectroscopy (XPS) results indicated the coatings' hydrophobicity was also influenced by surface chemistry. The FTIR-ATR characterization results showed there was remarkable increase in the crystallinity of 0.10 g FDTS-modified coating after modification, and was confirmed by differential scanning calorimetry (DSC) analysis of crystallization temperature and the X-ray diffraction (XRD) results with an estimation of 71.29% percent crystallinity. The mechanical properties of the coatings were also conducted. The EIS measurements for anti-corrosion behavior showed that 0.10 g FDTS-modified coating had the highest barrier performance and lowest rate of degradation. Indeed, the obtained data have demonstrated that 0.10 g (approximate to 0.18%) FDTS produced the most significantly effect on the surface and barrier properties of the coatings and thus, can effectively be used for anti-corrosion application in the marine environments. (C) 2017 Elsevier B.V. All rights reserved.; Poly(dimethylsiloxane)-ZnO coatings modified with different amounts of perfluorodecyltrichlorosilane (FDTS) were prepared using sol-gel technique. The results of field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM) examinations showed that the surface structures and roughness of the coatings were respectively influenced by the increasing addition of FDTS. The water contact angle measurements showed maximum value of 130.52 degrees with the 0.10 g FDTS-modified coating sample. The X-ray photoelectron spectroscopy (XPS) results indicated the coatings' hydrophobicity was also influenced by surface chemistry. The FTIR-ATR characterization results showed there was remarkable increase in the crystallinity of 0.10 g FDTS-modified coating after modification, and was confirmed by differential scanning calorimetry (DSC) analysis of crystallization temperature and the X-ray diffraction (XRD) results with an estimation of 71.29% percent crystallinity. The mechanical properties of the coatings were also conducted. The EIS measurements for anti-corrosion behavior showed that 0.10 g FDTS-modified coating had the highest barrier performance and lowest rate of degradation. Indeed, the obtained data have demonstrated that 0.10 g (approximate to 0.18%) FDTS produced the most significantly effect on the surface and barrier properties of the coatings and thus, can effectively be used for anti-corrosion application in the marine environments. (C) 2017 Elsevier B.V. All rights reserved.
部门归属	[arukalam, innocent o. ; meng, meijiang ; xiao, haigang ; ma, yuantai ; li, ying] chinese acad sci, inst met res, 62 wencui rd, shenyang 110016, liaoning, peoples r china ; [arukalam, innocent o.] fed univ technol owerri, dept polymer & text engn, pmb 1526, owerri, nigeria ; [arukalam, innocent o. ; oguzie, emeka e.] fed univ technol owerri, dept chem, electrochem & mat sci res lab, pmb 1526, owerri, nigeria
关键词	Mechanical-properties Corrosion Protection Epoxy Coatings Zno Fabrication Carbon Water Polydimethylsiloxane Nanoparticles Hybrid
学科领域	Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
资助者	Chinese Academy of Sciences-Presidentapos;s International Fellowship Initiative (CAS-PIFI) for Postdoctoral Research, China [2015PT005]; National Natural Science Foundation of China (NSFC) [51650110506]
收录类别	SCI
语种	英语
WOS记录号	WOS:000418883800135
引用统计	被引频次：33[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/79456
专题	中国科学院金属研究所
通讯作者	Li, Y (reprint author), Chinese Acad Sci, Inst Met Res, 62 Wencui Rd, Shenyang 110016, Liaoning, Peoples R China.
推荐引用方式 GB/T 7714	Arukalam, IO,Meng, MJ,Xiao, HG,et al. Effect of perfluorodecyltrichlorosilane on the surface properties and anti-corrosion behavior of poly(dimethylsiloxane)-ZnO coatings[J]. APPLIED SURFACE SCIENCE,2018,433:1113-1127.
APA	Arukalam, IO.,Meng, MJ.,Xiao, HG.,Ma, YT.,Oguzie, EE.,...&Li, Y .(2018).Effect of perfluorodecyltrichlorosilane on the surface properties and anti-corrosion behavior of poly(dimethylsiloxane)-ZnO coatings.APPLIED SURFACE SCIENCE,433,1113-1127.
MLA	Arukalam, IO,et al."Effect of perfluorodecyltrichlorosilane on the surface properties and anti-corrosion behavior of poly(dimethylsiloxane)-ZnO coatings".APPLIED SURFACE SCIENCE 433(2018):1113-1127.