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Few-layer sp(2) carbon supported on Al2O3 as hybrid structure for ethylbenzene oxidative dehydrogenation
Wang, J; Diao, JY; Zhang, JY; Zhang, YJ; Liu, HY; Su, DS; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China.
2018-03-01
发表期刊CATALYSIS TODAY
ISSN0920-5861
卷号301页码:32-37
摘要Hybrid materials consisting of few-layer sp(2) carbon supported on Al2O3 can potentially display comparable performance with nanodiamonds for the oxidative dehydrogenation of ethylbenzene. The hybrid structure could be easily prepared by fast coking method using ethanol as a precursor and gamma-Al2O3 with high specific surface areas as a template. In this case, gamma-Al2O3 plays the role of 3D support for depositing few-layer graphene-like structure. The hybrid structure exhibiting similar structure with nanodiamonds calcined at high temperature is further used as a metal-free catalyst for the oxidative dehydrogenation of ethylbenzene to styrene. The yield rate of styrene normalized by the specific area on Al2O3@C is 0.044 mmol m(-2) h(-1) (TOF = 4.13 h(-1)) which is two times of that on nanodiamonds (0.020 mmol m(-2) h(-1), TOF = 3.27 h(-1)). Considering the low cost process and good catalytic performance, the hybrid nanostructure may be a promising candidate to be applied in the oxidative dehydrogenation of ethylbenzene. (C) 2017 Elsevier B.V. All rights reserved.; Hybrid materials consisting of few-layer sp(2) carbon supported on Al2O3 can potentially display comparable performance with nanodiamonds for the oxidative dehydrogenation of ethylbenzene. The hybrid structure could be easily prepared by fast coking method using ethanol as a precursor and gamma-Al2O3 with high specific surface areas as a template. In this case, gamma-Al2O3 plays the role of 3D support for depositing few-layer graphene-like structure. The hybrid structure exhibiting similar structure with nanodiamonds calcined at high temperature is further used as a metal-free catalyst for the oxidative dehydrogenation of ethylbenzene to styrene. The yield rate of styrene normalized by the specific area on Al2O3@C is 0.044 mmol m(-2) h(-1) (TOF = 4.13 h(-1)) which is two times of that on nanodiamonds (0.020 mmol m(-2) h(-1), TOF = 3.27 h(-1)). Considering the low cost process and good catalytic performance, the hybrid nanostructure may be a promising candidate to be applied in the oxidative dehydrogenation of ethylbenzene. (C) 2017 Elsevier B.V. All rights reserved.
部门归属[wang, jia ; diao, jiangyong ; zhang, jiayun ; zhang, yajie ; liu, hongyang ; su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china ; [zhang, jiayun ; zhang, yajie] univ sci & technol china, sch chem & mat sci, hefei 230026, anhui, peoples r china
关键词Robust Catalytic Performance Ordered Mesoporous Carbon Facile Synthesis Nanocarbon Styrene
学科领域Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
资助者Ministry of Science and Technology (MOST) [2016YFA0204100]; National Natural Science Foundation of China [21573254, 91545110, 21133010, 51221264, 21261160487, 11504386, 21403261]; Youth Innovation Promotion Association (CAS); Sinopec China; MOST [2011CBA00504]; "Strategic Priority Research Program" of the Chinese Academy of Sciences [XDA09030103]
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/79481
专题中国科学院金属研究所
通讯作者Liu, HY; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China.
推荐引用方式
GB/T 7714
Wang, J,Diao, JY,Zhang, JY,et al. Few-layer sp(2) carbon supported on Al2O3 as hybrid structure for ethylbenzene oxidative dehydrogenation[J]. CATALYSIS TODAY,2018,301:32-37.
APA Wang, J.,Diao, JY.,Zhang, JY.,Zhang, YJ.,Liu, HY.,...&Su, DS .(2018).Few-layer sp(2) carbon supported on Al2O3 as hybrid structure for ethylbenzene oxidative dehydrogenation.CATALYSIS TODAY,301,32-37.
MLA Wang, J,et al."Few-layer sp(2) carbon supported on Al2O3 as hybrid structure for ethylbenzene oxidative dehydrogenation".CATALYSIS TODAY 301(2018):32-37.
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