| The facile synthesis, crystallization behavior and magnetic property of FeNiP amorphous nanoparticles | |
| Yuan, J; Li, CF; Yang, B; Liu, ZQ; Liu, ZQ (reprint author), Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China. | |
| 2018-02-01 | |
| Source Publication | MATERIALS CHARACTERIZATION
 |
| ISSN | 1044-5803 |
| Volume | 136Pages:94-99 |
| Abstract | Amorphous FeNiP nanoparticles with homogeneous composition are synthesized by reduction of aqueous Fe2+ and Ni2+ with sodium borohydride (NaBH4) and hypophosphite at room temperature. These amorphous nanoparticles can be crystallized by heating up to 300 degrees C to form FeNi3 and Ni3P crystals. Ni phase appeared at the sintering temperature of 500 degrees C, and a special net structure was formed at 700 degrees C due to the joining and diffusion among different nanoparticles. At a higher temperature of 800 degrees C, phase transformation happened and only pure Ni nanospheres and monoclinic ((Ni, Fe)(3)[PO4](2)) nanorods can be observed, which should be governed by the long-range diffusion in the net structure. The amorphous FeNiP nanoparticles have excellent soft magnetic property with Ms of 13.2 emu/g and He of 0.7 Oe. However, the sintered mixing nanoparticles show varied magnetic properties due to the phase transformation and proportion change among different phases involved in.; Amorphous FeNiP nanoparticles with homogeneous composition are synthesized by reduction of aqueous Fe2+ and Ni2+ with sodium borohydride (NaBH4) and hypophosphite at room temperature. These amorphous nanoparticles can be crystallized by heating up to 300 degrees C to form FeNi3 and Ni3P crystals. Ni phase appeared at the sintering temperature of 500 degrees C, and a special net structure was formed at 700 degrees C due to the joining and diffusion among different nanoparticles. At a higher temperature of 800 degrees C, phase transformation happened and only pure Ni nanospheres and monoclinic ((Ni, Fe)(3)[PO4](2)) nanorods can be observed, which should be governed by the long-range diffusion in the net structure. The amorphous FeNiP nanoparticles have excellent soft magnetic property with Ms of 13.2 emu/g and He of 0.7 Oe. However, the sintered mixing nanoparticles show varied magnetic properties due to the phase transformation and proportion change among different phases involved in. |
| description.department | [yuan, jie ; li, cai-fu ; liu, zhi-quan] chinese acad sci, inst met res, shenyang 110016, liaoning, peoples r china ; [yuan, jie ; liu, zhi-quan] univ sci & technol china, sch mat sci & engn, shenyang 110016, liaoning, peoples r china ; [yang, bo] northeastern univ, sch mat sci & engn, minist educ, key lab anisotropy & texture mat, shenyang 110819, liaoning, peoples r china ; [li, cai-fu ; liu, zhi-quan] osaka univ, inst sci & ind res, osaka 5670047, japan |
| Keyword | High Saturation Magnetization Interfacial Reliability Alloys Temperature Fabrication Relaxation |
| Subject Area | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Materials Science, Characterization & Testing |
| Funding Organization | National Key Research and Development Program of China [2017YFB0305501]; National Natural Science Foundation of China [51601033]; Osaka University Visiting Scholar Program [J135104902] |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000425075700010 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/79541 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, ZQ (reprint author), Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China. |
| Recommended Citation GB/T 7714 | Yuan, J,Li, CF,Yang, B,et al. The facile synthesis, crystallization behavior and magnetic property of FeNiP amorphous nanoparticles[J]. MATERIALS CHARACTERIZATION,2018,136:94-99. |
| APA | Yuan, J,Li, CF,Yang, B,Liu, ZQ,&Liu, ZQ .(2018).The facile synthesis, crystallization behavior and magnetic property of FeNiP amorphous nanoparticles.MATERIALS CHARACTERIZATION,136,94-99. |
| MLA | Yuan, J,et al."The facile synthesis, crystallization behavior and magnetic property of FeNiP amorphous nanoparticles".MATERIALS CHARACTERIZATION 136(2018):94-99. |
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