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The facile synthesis, crystallization behavior and magnetic property of FeNiP amorphous nanoparticles
Yuan, J; Li, CF; Yang, B; Liu, ZQ; Liu, ZQ (reprint author), Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China.
2018-02-01
发表期刊MATERIALS CHARACTERIZATION
ISSN1044-5803
卷号136页码:94-99
摘要Amorphous FeNiP nanoparticles with homogeneous composition are synthesized by reduction of aqueous Fe2+ and Ni2+ with sodium borohydride (NaBH4) and hypophosphite at room temperature. These amorphous nanoparticles can be crystallized by heating up to 300 degrees C to form FeNi3 and Ni3P crystals. Ni phase appeared at the sintering temperature of 500 degrees C, and a special net structure was formed at 700 degrees C due to the joining and diffusion among different nanoparticles. At a higher temperature of 800 degrees C, phase transformation happened and only pure Ni nanospheres and monoclinic ((Ni, Fe)(3)[PO4](2)) nanorods can be observed, which should be governed by the long-range diffusion in the net structure. The amorphous FeNiP nanoparticles have excellent soft magnetic property with Ms of 13.2 emu/g and He of 0.7 Oe. However, the sintered mixing nanoparticles show varied magnetic properties due to the phase transformation and proportion change among different phases involved in.; Amorphous FeNiP nanoparticles with homogeneous composition are synthesized by reduction of aqueous Fe2+ and Ni2+ with sodium borohydride (NaBH4) and hypophosphite at room temperature. These amorphous nanoparticles can be crystallized by heating up to 300 degrees C to form FeNi3 and Ni3P crystals. Ni phase appeared at the sintering temperature of 500 degrees C, and a special net structure was formed at 700 degrees C due to the joining and diffusion among different nanoparticles. At a higher temperature of 800 degrees C, phase transformation happened and only pure Ni nanospheres and monoclinic ((Ni, Fe)(3)[PO4](2)) nanorods can be observed, which should be governed by the long-range diffusion in the net structure. The amorphous FeNiP nanoparticles have excellent soft magnetic property with Ms of 13.2 emu/g and He of 0.7 Oe. However, the sintered mixing nanoparticles show varied magnetic properties due to the phase transformation and proportion change among different phases involved in.
部门归属[yuan, jie ; li, cai-fu ; liu, zhi-quan] chinese acad sci, inst met res, shenyang 110016, liaoning, peoples r china ; [yuan, jie ; liu, zhi-quan] univ sci & technol china, sch mat sci & engn, shenyang 110016, liaoning, peoples r china ; [yang, bo] northeastern univ, sch mat sci & engn, minist educ, key lab anisotropy & texture mat, shenyang 110819, liaoning, peoples r china ; [li, cai-fu ; liu, zhi-quan] osaka univ, inst sci & ind res, osaka 5670047, japan
关键词High Saturation Magnetization Interfacial Reliability Alloys Temperature Fabrication Relaxation
学科领域Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Materials Science, Characterization & Testing
资助者National Key Research and Development Program of China [2017YFB0305501]; National Natural Science Foundation of China [51601033]; Osaka University Visiting Scholar Program [J135104902]
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/79541
专题中国科学院金属研究所
通讯作者Liu, ZQ (reprint author), Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China.
推荐引用方式
GB/T 7714
Yuan, J,Li, CF,Yang, B,et al. The facile synthesis, crystallization behavior and magnetic property of FeNiP amorphous nanoparticles[J]. MATERIALS CHARACTERIZATION,2018,136:94-99.
APA Yuan, J,Li, CF,Yang, B,Liu, ZQ,&Liu, ZQ .(2018).The facile synthesis, crystallization behavior and magnetic property of FeNiP amorphous nanoparticles.MATERIALS CHARACTERIZATION,136,94-99.
MLA Yuan, J,et al."The facile synthesis, crystallization behavior and magnetic property of FeNiP amorphous nanoparticles".MATERIALS CHARACTERIZATION 136(2018):94-99.
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