Crystallization kinetics of PbTiO3 ferroelectric films: Comparison of microwave irradiation with conventional heating

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	Crystallization kinetics of PbTiO3 ferroelectric films: Comparison of microwave irradiation with conventional heating
	Zhang, YJ; Wang, ZJ; Chen, YN; Zhang, ZD; Wang, ZJ (reprint author), Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China.
	2018
发表期刊	JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
ISSN	0955-2219
卷号	38 期号:1 页码:105-111
摘要	Lead titanate (PTO) films were deposited onto Pt/Ti/SiO2/Si substrates by a sol-gel method and annealed by microwave irradiation and conventional heating. In contrast to conventional heating, microwave irradiation can crystallize the PTO films at a low temperature of 450 degrees C or at 550 degrees C for only 5 min. The XRD and TEM studies reveal that microwave radiation can reduce the nucleation time, and increase the growth rate of perovskite grains in the crystallization process. Moreover, the results using the Avrami's model show that the effective activation energy for crystallization process by microwave irradiation is 131 kJ/mol, much lower than that for the PTO films by conventional heating (216 kJ/mol). Therefore, microwave irradiation can reduce the effective activation energy for the nucleation and grain growth of the perovskite phase during the crystallization process, contributing to a low-temperature or a short-time preparation process of ferroelectric films.; Lead titanate (PTO) films were deposited onto Pt/Ti/SiO2/Si substrates by a sol-gel method and annealed by microwave irradiation and conventional heating. In contrast to conventional heating, microwave irradiation can crystallize the PTO films at a low temperature of 450 degrees C or at 550 degrees C for only 5 min. The XRD and TEM studies reveal that microwave radiation can reduce the nucleation time, and increase the growth rate of perovskite grains in the crystallization process. Moreover, the results using the Avrami's model show that the effective activation energy for crystallization process by microwave irradiation is 131 kJ/mol, much lower than that for the PTO films by conventional heating (216 kJ/mol). Therefore, microwave irradiation can reduce the effective activation energy for the nucleation and grain growth of the perovskite phase during the crystallization process, contributing to a low-temperature or a short-time preparation process of ferroelectric films.
部门归属	[zhang, ya-ju ; wang, zhan jie ; chen, yan na ; zhang, zhi dong] chinese acad sci, shenyang natl lab mat sci, inst met res, 72 wenhua rd, shenyang 110016, liaoning, peoples r china ; [zhang, ya-ju ; wang, zhan jie ; zhang, zhi dong] univ chinese acad sci, beijing 100049, peoples r china ; [wang, zhan jie] shenyang univ technol, sch mat sci & engn, shenyang 110870, liaoning, peoples r china
关键词	Titanate Thin-films Low-temperature In-situ State Photocatalysis Precursors Chemistry Ceramics Graphene Equation
学科领域	Materials Science, Ceramics
资助者	Hundred Talents Program of Chinese Academy of Sciences; National Natural Science of Foundation of China [51172238, 51502303]
收录类别	SCI
语种	英语
WOS记录号	WOS:000414117500010
引用统计	被引频次：11[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/79629
专题	中国科学院金属研究所
通讯作者	Wang, ZJ (reprint author), Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China.
推荐引用方式 GB/T 7714	Zhang, YJ,Wang, ZJ,Chen, YN,et al. Crystallization kinetics of PbTiO3 ferroelectric films: Comparison of microwave irradiation with conventional heating[J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,2018,38(1):105-111.
APA	Zhang, YJ,Wang, ZJ,Chen, YN,Zhang, ZD,&Wang, ZJ .(2018).Crystallization kinetics of PbTiO3 ferroelectric films: Comparison of microwave irradiation with conventional heating.JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,38(1),105-111.
MLA	Zhang, YJ,et al."Crystallization kinetics of PbTiO3 ferroelectric films: Comparison of microwave irradiation with conventional heating".JOURNAL OF THE EUROPEAN CERAMIC SOCIETY 38.1(2018):105-111.