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Encapsulation of metal oxide nanoparticles inside metal-organic frameworks via surfactant-assisted nanoconfined space
Wang,Sha1; Yu,Yantao1; Yu,Jinqiu1; Wang,Tieqiang1; Wang,Peng1; Li,Yunong1; Zhang,Xuemin1; Zhang,Liying1; Hu,Zhuang1; Chen,Junyi3; Fu,Yu1; Qi,Wei2
2020-04-03
发表期刊Nanotechnology
ISSN0957-4484
卷号31期号:25
摘要Abstract Encapsulation of metal oxide nanoparticles (MO NPs) inside metal-organic frameworks (MOFs) has been realized successfully via surfactant-assisted nano-confined space strategy, which is a universal method for various MO NPs@MOFs. The size of MO NPs was limited by the confined nano-space and could be adjusted to a certain extent. The synthesis mechanism of MO NPs@MOFs was revealed via detailed structural characterizations and a series of control experiments. Surfactants introduced during MOFs (CuBDC, BDC?=?1,4-benzenedicarboxylic acid) formation process plays a very important role in producing uniform voids of nano-confined space. Cu ions in MOF frameworks were directly used as precursors to fabricate CuO NPs in these confined void spaces. The synthesized CuO@CuBDC composites showed excellent catalytic activity in C-S cross-coupling reactions and dye pollutant photo-degradation reactions.
关键词metal oxide nanoparticles metal-organic frameworks encapsulations nano-confined spaces
DOI10.1088/1361-6528/ab79ae
语种英语
WOS记录号IOP:0957-4484-31-25-ab79ae
出版者IOP Publishing
引用统计
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/80655
专题中国科学院金属研究所
作者单位1.Department of Chemistry, College of Sciences, Northeastern University, Shenyang, 110819, People’s Republic of China
2.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, People’s Republic of China
3.Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, College of Life Science, Tarim University, Xinjiang Uygur Autonomous Region, Alaer, 843300, People’s Republic of China
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GB/T 7714
Wang,Sha,Yu,Yantao,Yu,Jinqiu,et al. Encapsulation of metal oxide nanoparticles inside metal-organic frameworks via surfactant-assisted nanoconfined space[J]. Nanotechnology,2020,31(25).
APA Wang,Sha.,Yu,Yantao.,Yu,Jinqiu.,Wang,Tieqiang.,Wang,Peng.,...&Qi,Wei.(2020).Encapsulation of metal oxide nanoparticles inside metal-organic frameworks via surfactant-assisted nanoconfined space.Nanotechnology,31(25).
MLA Wang,Sha,et al."Encapsulation of metal oxide nanoparticles inside metal-organic frameworks via surfactant-assisted nanoconfined space".Nanotechnology 31.25(2020).
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