Encapsulation of metal oxide nanoparticles inside metal-organic frameworks via surfactant-assisted nanoconfined space | |
Wang,Sha1; Yu,Yantao1; Yu,Jinqiu1; Wang,Tieqiang1; Wang,Peng1; Li,Yunong1; Zhang,Xuemin1; Zhang,Liying1; Hu,Zhuang1; Chen,Junyi3; Fu,Yu1; Qi,Wei2 | |
2020-04-03 | |
发表期刊 | Nanotechnology
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ISSN | 0957-4484 |
卷号 | 31期号:25 |
摘要 | Abstract Encapsulation of metal oxide nanoparticles (MO NPs) inside metal-organic frameworks (MOFs) has been realized successfully via surfactant-assisted nano-confined space strategy, which is a universal method for various MO NPs@MOFs. The size of MO NPs was limited by the confined nano-space and could be adjusted to a certain extent. The synthesis mechanism of MO NPs@MOFs was revealed via detailed structural characterizations and a series of control experiments. Surfactants introduced during MOFs (CuBDC, BDC?=?1,4-benzenedicarboxylic acid) formation process plays a very important role in producing uniform voids of nano-confined space. Cu ions in MOF frameworks were directly used as precursors to fabricate CuO NPs in these confined void spaces. The synthesized CuO@CuBDC composites showed excellent catalytic activity in C-S cross-coupling reactions and dye pollutant photo-degradation reactions. |
关键词 | metal oxide nanoparticles metal-organic frameworks encapsulations nano-confined spaces |
DOI | 10.1088/1361-6528/ab79ae |
语种 | 英语 |
WOS记录号 | IOP:0957-4484-31-25-ab79ae |
出版者 | IOP Publishing |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/80655 |
专题 | 中国科学院金属研究所 |
作者单位 | 1.Department of Chemistry, College of Sciences, Northeastern University, Shenyang, 110819, People’s Republic of China 2.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, People’s Republic of China 3.Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, College of Life Science, Tarim University, Xinjiang Uygur Autonomous Region, Alaer, 843300, People’s Republic of China |
推荐引用方式 GB/T 7714 | Wang,Sha,Yu,Yantao,Yu,Jinqiu,et al. Encapsulation of metal oxide nanoparticles inside metal-organic frameworks via surfactant-assisted nanoconfined space[J]. Nanotechnology,2020,31(25). |
APA | Wang,Sha.,Yu,Yantao.,Yu,Jinqiu.,Wang,Tieqiang.,Wang,Peng.,...&Qi,Wei.(2020).Encapsulation of metal oxide nanoparticles inside metal-organic frameworks via surfactant-assisted nanoconfined space.Nanotechnology,31(25). |
MLA | Wang,Sha,et al."Encapsulation of metal oxide nanoparticles inside metal-organic frameworks via surfactant-assisted nanoconfined space".Nanotechnology 31.25(2020). |
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