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Synergistic effect of surface plane and particle sizes on the electrochemical performance of LiNi0.5Mn1.5O4 cathode material via a facile calcination process
Shu, Yang; Xie, Yin; Yan, Wenchao; Meng, Su; Sun, Deye; Jin, Yongcheng; He, Kuang
2019-09-01
Source PublicationJOURNAL OF POWER SOURCES
ISSN0378-7753
Volume433
AbstractA series of LiNi0.5Mn1.5O4 cathode samples with different morphologies was synthesized via a template method and facile post-calcination process. Rod-like and truncated octahedral particles with {111} surface are obtained through increasing the calcination temperature. The exposed surface of as-prepared materials is mainly detected by SEM and TEM images. Detailed characterization of electrochemical performance of samples reflects that the T-775 cathode sample displays superior rate capability, and the discharge capacity reaches 108.2 mAh g(-1) at 100C. The energy density of full cells, T-775 sample as the cathode material and commercial graphite as the anode material, retain 534.9 Wh kg(-1) after 100 cycles. These improvements might be due to the synergistic effect of the {111} surface and smaller particle sizes, which improves interfacial stability and reduces the diffusion distance of Li+ during the interaction/deinteraction process.
Indexed BySCI
Language英语
WOS IDWOS:000480670200027
PublisherELSEVIER
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/80792
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
Shu, Yang,Xie, Yin,Yan, Wenchao,et al. Synergistic effect of surface plane and particle sizes on the electrochemical performance of LiNi0.5Mn1.5O4 cathode material via a facile calcination process[J]. JOURNAL OF POWER SOURCES,2019,433.
APA Shu, Yang.,Xie, Yin.,Yan, Wenchao.,Meng, Su.,Sun, Deye.,...&He, Kuang.(2019).Synergistic effect of surface plane and particle sizes on the electrochemical performance of LiNi0.5Mn1.5O4 cathode material via a facile calcination process.JOURNAL OF POWER SOURCES,433.
MLA Shu, Yang,et al."Synergistic effect of surface plane and particle sizes on the electrochemical performance of LiNi0.5Mn1.5O4 cathode material via a facile calcination process".JOURNAL OF POWER SOURCES 433(2019).
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