Studies of the g factor for Cr4+ ion in Bi4Ge3O12 crystal from crystal-field and charge-transfer mechanisms

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	Studies of the g factor for Cr4+ ion in Bi4Ge3O12 crystal from crystal-field and charge-transfer mechanisms
	Wu, XX ; Zheng, WC ; Tang, S
通讯作者	Zheng, WC()
	2004-07-01
发表期刊	ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN	0932-0784
卷号	59 期号:7-8 页码:467-470
摘要	The complete third-order perturbation formulas of the g factors g(\\) and g(perpendicular to) for 3d(2) ions in tetragonal MX4 clusters have been obtained by a cluster approach. In these formulas, in addition to contributions to the g factors from the crystal-field mechanism in the crystal-field theory, the contributions from the charge-transfer mechanism are included. From these formulas, the g factors g(\\) and g(perpendicular to) for a Cr4+ ion in a Bi4Ge3O12 crystal are calculated. The results agree with the observed values. The calculated Deltag(i)(i = \\ or perpendicular to) value due to the charge-transfer is opposite in sign and about 20% greater than that due to the crystal-field mechanism. So, for the 3d(n) ions having a high valence in crystals, a reasonable explanation of the g factors should take both the crystal-field and charge-transfer mechanisms into account.
关键词	electron paramagnetic resonance crystal- and ligand- field theory charge-transfer mechanism Cr4+ Bi4Ge3O12
收录类别	SCI
语种	英语
WOS研究方向	Chemistry ; Physics
WOS类目	Chemistry, Physical ; Physics, Multidisciplinary
WOS记录号	WOS:000223471600009
出版者	VERLAG Z NATURFORSCH
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/80795
通讯作者	Zheng, WC
作者单位	1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Civil Aviat Flying Inst China, Dept Phys, Gunghan 618307, Peoples R China 3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Wu, XX,Zheng, WC,Tang, S. Studies of the g factor for Cr4+ ion in Bi4Ge3O12 crystal from crystal-field and charge-transfer mechanisms[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,2004,59(7-8):467-470.
APA	Wu, XX,Zheng, WC,&Tang, S.(2004).Studies of the g factor for Cr4+ ion in Bi4Ge3O12 crystal from crystal-field and charge-transfer mechanisms.ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,59(7-8),467-470.
MLA	Wu, XX,et al."Studies of the g factor for Cr4+ ion in Bi4Ge3O12 crystal from crystal-field and charge-transfer mechanisms".ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 59.7-8(2004):467-470.