Lithiation of Silicon Nanoparticles Confined in Carbon Nanotubes

doi:10.1021/acsnano.5b00157

IMR OpenIR

	Lithiation of Silicon Nanoparticles Confined in Carbon Nanotubes
	Yu, Wan-Jing; Liu, Chang; Hou, Peng-Xiang; Zhang, Lili; Shan, Xu-Yi; Li, Feng; Cheng, Hui-Ming
通讯作者	Liu, Chang(cliu@imr.ac.cn)
	2015-05-01
发表期刊	ACS NANO
ISSN	1936-0851
卷号	9 期号:5 页码:5063-5071
摘要	Silicon has the highest theoretical lithium storage capacity of all materials at 4200 mAh/g; therefore, it is considered to be a promising candidate as the anode of high-energy-density lithium-ion batteries (LIBs). However, serious volume changes caused by lithium insertion/deinsertion lead to a rapid decay of the performance of the Si anode. Here, a Si nanoparticle (NP)-filled carbon nanotube (CNT) material was prepared by chemical vapor deposition, and a nanobattery was constnicted inside a transmission electron microscope (TEM) using the Si NP-filled CNT as working electrode to directly investigate the structural change of the Si NPs and the confinement effect of the CNT during the lithiation and delithiation processes. It is found that the volume expansion (similar to 180%) of the lithiated Si NPs is restricted by the wall of the CNTs and that the CNT can accommodate this volume expansion without breaking its tubular structure. The Si NP-filled CNTs showed a high reversible lithium storage capacity and desirable high rate capability, because the pulverization and exfoliation of the Si NPs confined in CNTs were efficiently prevented. Our results demonstrate that filling CNTs with high-capacity active materials is a feasible way to make high-performance LIB electrode materials, taking advantage of the unique confinement effect and good electrical conductivity of the CNTs.
关键词	lithium-ion batteries silicon nanoparticles carbon nanotubes confinement effect in situ TEM
资助者	Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences
DOI	10.1021/acsnano.5b00157
收录类别	SCI
语种	英语
资助项目	Ministry of Science and Technology of China[2011CB932601] ; Ministry of Science and Technology of China[2011CB932604] ; National Natural Science Foundation of China[51221264] ; National Natural Science Foundation of China[51272257] ; National Natural Science Foundation of China[51102242] ; Chinese Academy of Sciences[KGZD-EW-T06]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000355383000042
出版者	AMER CHEMICAL SOC
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/81156
通讯作者	Liu, Chang
作者单位	Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Yu, Wan-Jing,Liu, Chang,Hou, Peng-Xiang,et al. Lithiation of Silicon Nanoparticles Confined in Carbon Nanotubes[J]. ACS NANO,2015,9(5):5063-5071.
APA	Yu, Wan-Jing.,Liu, Chang.,Hou, Peng-Xiang.,Zhang, Lili.,Shan, Xu-Yi.,...&Cheng, Hui-Ming.(2015).Lithiation of Silicon Nanoparticles Confined in Carbon Nanotubes.ACS NANO,9(5),5063-5071.
MLA	Yu, Wan-Jing,et al."Lithiation of Silicon Nanoparticles Confined in Carbon Nanotubes".ACS NANO 9.5(2015):5063-5071.