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Direct observation of solid-state reversed transformation from crystals to quasicrystals in a Mg alloy
Liu, Jian-Fang; Yang, Zhi-Qing; Ye, Heng-Qiang
通讯作者Yang, Zhi-Qing(yangzq@imr.ac.cn)
2015-06-12
发表期刊SCIENTIFIC REPORTS
ISSN2045-2322
卷号5页码:10
摘要Phase transformation of quasicrystals is of interest in various fields of science and technology. Interestingly, we directly observed unexpected solid-state epitaxial nucleation and growth of Zn6Mg3Y icosahedral quasicrystals in a Mg alloy at about 573 K which is about 300 K below the melting point of Zn6Mg3Y, in contrast to formation of quasicrystals through solidification that was usually found in many alloys. Maximizing local packing density of atoms associated with segregation of Y and Zn in Mg adjacent to Mg/Zn3MgY interfaces triggered atomic rearrangement in Mg to form icosahedra coupled epitaxially with surface distorted icosahedra of Zn3MgY, which plays a critical role in the nucleation of icosahedral clusters. A local Zn: Mg: Y ratio close to 6:3:1, corresponding to a valence electron concentration of about 2.15, should have been reached to trigger the formation of quasicrystals at Mg/Zn3MgY interfaces. The solid-state icosahedral ordering in crystals opens a new window for growing quasicrystals and understanding their atomic origin mechanisms. Epitaxial growth of quasicrystals onto crystals can modify the surface/interface structures and properties of crystalline materials.
资助者National Nature Science Foundation of China
DOI10.1038/srep09816
收录类别SCI
语种英语
资助项目National Nature Science Foundation of China[51171189] ; National Nature Science Foundation of China[51371178] ; National Nature Science Foundation of China[51390473]
WOS研究方向Science & Technology - Other Topics
WOS类目Multidisciplinary Sciences
WOS记录号WOS:000356134700001
出版者NATURE PUBLISHING GROUP
引用统计
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/81183
通讯作者Yang, Zhi-Qing
作者单位Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China
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GB/T 7714
Liu, Jian-Fang,Yang, Zhi-Qing,Ye, Heng-Qiang. Direct observation of solid-state reversed transformation from crystals to quasicrystals in a Mg alloy[J]. SCIENTIFIC REPORTS,2015,5:10.
APA Liu, Jian-Fang,Yang, Zhi-Qing,&Ye, Heng-Qiang.(2015).Direct observation of solid-state reversed transformation from crystals to quasicrystals in a Mg alloy.SCIENTIFIC REPORTS,5,10.
MLA Liu, Jian-Fang,et al."Direct observation of solid-state reversed transformation from crystals to quasicrystals in a Mg alloy".SCIENTIFIC REPORTS 5(2015):10.
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