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Stability of K2FeO4 in dilute KOH solution
Yang, WH; Wang, JM; Cao, JL; Pan, T; Zhang, JQ; Cao, CN
Corresponding AuthorYang, WH(wjm@cmsce.zju.edu.cn)
2004-10-14
Source PublicationACTA CHIMICA SINICA
ISSN0567-7351
Volume62Issue:19Pages:1951-1955
AbstractThe stability of K2FeO4 in dilute KOH solution with initial pH value from 8.0 to 13.0 was studied in detail by spectrophotometry method in this paper. The decomposition rate of aqueous solution of K2FeO4 is basically regulated by its concentration, pH and the decomposed product FeOOH that can catalyze the decomposition of K2FeO4. The increase of HO- concentration can improve the stability of K2FeO4 by decreasing the collision frequency between FeO42- ions. However, when the concentration of HO- reaches a certain value, the decomposition product FeOOH is easily produced. FeOOH can catalyze the decomposition of K2FeO4. It was found that K2FeO4 is the most stable in the pH region of 10.0 similar to 11.0 and the decomposition rate of K2FeO4 is in the first order in the initial period. The decomposition rule of K2FeO4 along with its concentration in KOH solution is related with the initial pH of the solution.
KeywordK2FeO4 stability spectrophotometry method
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000224536500018
PublisherSCIENCE CHINA PRESS
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/81281
Corresponding AuthorYang, WH
Affiliation1.Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
2.Huaqiao Univ, Coll Mat Sci & Engn, Quanzhou 362011, Peoples R China
3.Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110015, Peoples R China
Recommended Citation
GB/T 7714
Yang, WH,Wang, JM,Cao, JL,et al. Stability of K2FeO4 in dilute KOH solution[J]. ACTA CHIMICA SINICA,2004,62(19):1951-1955.
APA Yang, WH,Wang, JM,Cao, JL,Pan, T,Zhang, JQ,&Cao, CN.(2004).Stability of K2FeO4 in dilute KOH solution.ACTA CHIMICA SINICA,62(19),1951-1955.
MLA Yang, WH,et al."Stability of K2FeO4 in dilute KOH solution".ACTA CHIMICA SINICA 62.19(2004):1951-1955.
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