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Studies of the anion position parameter chi of the ternary semiconductor CuGaS2 by use of Ni+ ion probe
Wu, XX; Zheng, WC; Sheng, T; Zi, H
通讯作者Zheng, WC()
2004-03-15
发表期刊MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY
ISSN0921-5107
卷号107期号:2页码:186-188
摘要The anion position parameter chi of NiS4 cluster formed in the ternary semiconductor CuGaS2 by substitution of Ni+ for Cu+ has been determined by studying the optical spectra and EPR data for CuGaS2:Ni+. The result (chi approximate to 0.263(1)) is consistent with the mean value of the X-ray measurement results reported in two groups of references and also with the calculated value obtained from the conservation of tetrahedral bonds (CTB) plus eta = eta(tet) rule (where eta = c/2a). So, we suggest that the anion position parameter chi in pure CuGaS2 crystal is close to the above value obtained by use of Ni+ ion probe. The optical absorption bands and g factors g(parallel to), g(perpendicular to), of CuGaS2: Ni+ are therefore explained reasonably from the anion position parameter. (C) 2003 Elsevier B.V. All rights reserved.
关键词structural parameter electron paramagnetic resonance (EPR) optical spectrum crystal-field theory CuGaS2 Ni+
DOI10.1016/j.mseb.2003.11.002
收录类别SCI
语种英语
WOS研究方向Materials Science ; Physics
WOS类目Materials Science, Multidisciplinary ; Physics, Condensed Matter
WOS记录号WOS:000220274200014
出版者ELSEVIER SCIENCE SA
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/81345
通讯作者Zheng, WC
作者单位1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
3.Civil Aviat Flying Inst China, Dept Phys, Guanghan 618307, Peoples R China
4.Fudan Univ, Surface Phys Lab, Natl Key Lab, Shanghai 200433, Peoples R China
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Wu, XX,Zheng, WC,Sheng, T,et al. Studies of the anion position parameter chi of the ternary semiconductor CuGaS2 by use of Ni+ ion probe[J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY,2004,107(2):186-188.
APA Wu, XX,Zheng, WC,Sheng, T,&Zi, H.(2004).Studies of the anion position parameter chi of the ternary semiconductor CuGaS2 by use of Ni+ ion probe.MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY,107(2),186-188.
MLA Wu, XX,et al."Studies of the anion position parameter chi of the ternary semiconductor CuGaS2 by use of Ni+ ion probe".MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY 107.2(2004):186-188.
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