Theoretical investigations of the g factors and the local structures for the orthorhombic Nd3+ centers in the garnets | |
Wu, SY; Dong, HN | |
通讯作者 | Wu, SY(wushaoyi@netease.com) |
2005-05-03 | |
发表期刊 | JOURNAL OF ALLOYS AND COMPOUNDS
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ISSN | 0925-8388 |
卷号 | 393期号:1-2页码:46-50 |
摘要 | The EPR g factors g(x), g(y) and g(z) and the local structures for the orthorhombic Nd3+ centers in YAG, YGG and LuGG garnets are studied by using the perturbation formulas of the g factors for a 43 ion in orthorhombic symmetry. In these formulas, the contributions to the g factors arising from the second-order perturbation terms and the admixture of various energy levels are considered. Based on the analyses of the g factors, we find that the polar angles theta'(j) of the impurity-ligand bonds related to the Z-axis of the crystals in these Nd3+ centers are smaller than the host angles theta(j) in pure crystals, whereas the azimuthal angles phi'(j) related to the X-axis in the impurity centers are larger than the corresponding phi(j) in the hosts. The calculated g factors, particularly their anisotropies Delta g [= g(z) - (g(x) + g(y))/2] and delta g (= g(x) - g(y)) for Nd3+ in the gamets based on the above local angles show reasonable agreement with the observed values. (c) 2004 Elsevier B.V. All rights reserved. |
关键词 | electron paramagnetic resonance (EPR) defect structure crystal-field and spin hamiltonians Nd3+ garnets |
DOI | 10.1016/j.jallcom.2004.09.067 |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
WOS类目 | Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:000228716700010 |
出版者 | ELSEVIER SCIENCE SA |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/81999 |
通讯作者 | Wu, SY |
作者单位 | 1.Univ Elect Sci & Technol China, Dept Appl Phys, Chengdu 610054, Peoples R China 2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China 3.Chongqing Univ Posts & Telecommun, Coll Elect Engn, Chongqing 400065, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, SY,Dong, HN. Theoretical investigations of the g factors and the local structures for the orthorhombic Nd3+ centers in the garnets[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2005,393(1-2):46-50. |
APA | Wu, SY,&Dong, HN.(2005).Theoretical investigations of the g factors and the local structures for the orthorhombic Nd3+ centers in the garnets.JOURNAL OF ALLOYS AND COMPOUNDS,393(1-2),46-50. |
MLA | Wu, SY,et al."Theoretical investigations of the g factors and the local structures for the orthorhombic Nd3+ centers in the garnets".JOURNAL OF ALLOYS AND COMPOUNDS 393.1-2(2005):46-50. |
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