The internal oxidation of ternary alloys. V: The transition from internal to external oxidation of the most-reactive component under low oxidant pressures

IMR OpenIR

	The internal oxidation of ternary alloys. V: The transition from internal to external oxidation of the most-reactive component under low oxidant pressures
	Gesmundo, F ; Niu, Y
通讯作者	Niu, Y()
	2004-12-01
发表期刊	OXIDATION OF METALS
ISSN	0030-770X
卷号	62 期号:5-6 页码:375-390
摘要	This paper examines the conditions for the transition from internal to external oxidation of the most-reactive component C of ternary A-B C alloys by a single oxidant under gas-phase oxidant activities below the stability of the oxide of the two most-reactive components using Wagner's criterion. Tor this, approximate relations between the solubility and diffusivity of oxygen and the composition of the binary A-B alloy matrix in the zone of internal oxidation, already developed previously, are used. The critical C content needed for the transition in ternary alloys is calculated as a junction of the many parameters involved. At variance with the behavior of binary alloys, for ternary alloys this critical C content depends also on the ratio between the concentrations of A and B in the bulk alloy. The results calculated for ternary alloys are compared with those obtained for binary A-C and B-C alloys under the same values of all the relevant parameters. Finally, complete oxidation maps for ternary alloys under low oxidant pressures, including the condition for the stability of external scales of the C oxide, are also presented.
关键词	ternary alloys low oxidant pressures transition from internal oxidation
收录类别	SCI
语种	英语
WOS研究方向	Metallurgy & Metallurgical Engineering
WOS类目	Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000226001700005
出版者	KLUWER ACADEMIC/PLENUM PUBL
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/82317
通讯作者	Niu, Y
作者单位	1.CAS, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China 2.Univ Genoa, Dipartimento Ingn Chim & Proc, I-16129 Genoa, Italy
推荐引用方式 GB/T 7714	Gesmundo, F,Niu, Y. The internal oxidation of ternary alloys. V: The transition from internal to external oxidation of the most-reactive component under low oxidant pressures[J]. OXIDATION OF METALS,2004,62(5-6):375-390.
APA	Gesmundo, F,&Niu, Y.(2004).The internal oxidation of ternary alloys. V: The transition from internal to external oxidation of the most-reactive component under low oxidant pressures.OXIDATION OF METALS,62(5-6),375-390.
MLA	Gesmundo, F,et al."The internal oxidation of ternary alloys. V: The transition from internal to external oxidation of the most-reactive component under low oxidant pressures".OXIDATION OF METALS 62.5-6(2004):375-390.