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Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method
Wang, JF; Xiong, R; Yi, F; Yin, D; Ke, MZ; Li, CZ; Liu, ZY; Shi, J
Corresponding AuthorWang, JF(janson_iris@163.com)
2005-05-01
Source PublicationJOURNAL OF SOLID STATE CHEMISTRY
ISSN0022-4596
Volume178Issue:5Pages:1440-1444
AbstractHigh quality and large-sized Rb0.3MoO3 single crystals were synthesized by molten salt electrolysis method. X-ray diffraction (XRD) patterns and rocking curves, as well as the white beam Laue diffraction of X-ray images show the crystals grown by this method have high quality. The lattice constants evaluated from XRD patterns are a(0) = 1.87 nm, b(0) = 0.75 nm, c(0) = 1.00 nm, β = 118.83(°). The in situ selected area electron diffraction (SAED) patterns along the [10(1) over bar], [1 (11) over bar] and [10(3) over bar] zone axes at room temperature indicate that the Rb0.3MoO3 crystal possess perfect C-centered symmetry. Temperature dependence of the resistivity shows this compound undergoes a metal to semiconductor transition at 183 K. © 2005 Elsevier Inc. All rights reserved.
Keywordblue bronze Rb0.3MoO3 single crystal growth electrolytic reduction charge density wave
DOI10.1016/j.jssc.2005.02.015
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Physical
WOS IDWOS:000228934800012
PublisherACADEMIC PRESS INC ELSEVIER SCIENCE
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/82732
Corresponding AuthorWang, JF
Affiliation1.Wuhan Univ, Dept Phys, Wuhan 430072, Peoples R China
2.Int Ctr Mat Phys, Shenyang 110015, Peoples R China
Recommended Citation
GB/T 7714
Wang, JF,Xiong, R,Yi, F,et al. Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method[J]. JOURNAL OF SOLID STATE CHEMISTRY,2005,178(5):1440-1444.
APA Wang, JF.,Xiong, R.,Yi, F.,Yin, D.,Ke, MZ.,...&Shi, J.(2005).Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method.JOURNAL OF SOLID STATE CHEMISTRY,178(5),1440-1444.
MLA Wang, JF,et al."Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method".JOURNAL OF SOLID STATE CHEMISTRY 178.5(2005):1440-1444.
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