Determination of rhenium in raffinate and residue from synthesis of methyltrioxorhenium by ICP-AES

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	Determination of rhenium in raffinate and residue from synthesis of methyltrioxorhenium by ICP-AES
其他题名	Determination of Rhenium in Raffinate and Residue from Synthesis of Methyltrioxorhenium by ICP-AES
	Liu Ning 1; Zhang Shitao 2; Li Jun 1; Yue Shuang 2; Zang Shuliang 2
	2008
发表期刊	SPECTROSCOPY AND SPECTRAL ANALYSIS
ISSN	1000-0593
卷号	28 期号:7 页码:1650-1652
摘要	Methyltrioxorhenium is a novel and efficient organometallic catalyst. It has exhibited amazingly high activities in a variety of organic reactions, and can form compounds with Lewis base. Thus, the improvement of its synthesis rate has become a pop topic all over the world. The content of rhenium in raffinate and residue from the synthesis of methyltrioxorhenium is an important standard for the evaluation of synthesis rate and a foundation for the optimization of synthesis condition. UV spectrophotometry is the standard technique for the determination of rhenium. However, this method presents several disadvantanges such as low sensitivity, high interferences, and hard handling. Inductive coupled plasma-atomic emission spectrometry has many advantages such as high precision, rapid analysis speed and good stability, and can determine multi-elements simultaneously. It is widely used in determination in every walk of life. An ICP-AES method for determination of the content of rhenium in raffinate and residue from the synthesis of methyltrioxorhenium. was used. The working parameters were optimized. The detection limit was 0. 01 mg center dot L-1. RSD was in the range of 0. 48%-1. 12% and recoveries in the range from 97. 2%-104% were obtained. The spectrum interference can be neglected. Compared with spectrophotometer, the proposed method was proved to be simple, rapid and accurate, and the result was satisfactory.
关键词	ELEMENTS CATALYST ZN ICP-AES methyltrioxorhenium raffinate residue rhenium
收录类别	CSCD
语种	英语
CSCD记录号	CSCD:3331763
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/86738
专题	中国科学院金属研究所
作者单位	1.辽宁大学 2.中国科学院金属研究所
推荐引用方式 GB/T 7714	Liu Ning,Zhang Shitao,Li Jun,et al. Determination of rhenium in raffinate and residue from synthesis of methyltrioxorhenium by ICP-AES[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2008,28(7):1650-1652.
APA	Liu Ning,Zhang Shitao,Li Jun,Yue Shuang,&Zang Shuliang.(2008).Determination of rhenium in raffinate and residue from synthesis of methyltrioxorhenium by ICP-AES.SPECTROSCOPY AND SPECTRAL ANALYSIS,28(7),1650-1652.
MLA	Liu Ning,et al."Determination of rhenium in raffinate and residue from synthesis of methyltrioxorhenium by ICP-AES".SPECTROSCOPY AND SPECTRAL ANALYSIS 28.7(2008):1650-1652.