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Cluster-based composition rule for Laves phase-related BCC solid solution hydrogen storage alloys
Wang Qing; Chen Feng; Wu Jiang; Qiang Jianbing; Dong Chuang; Zhang Yao; Xu Fen; Sun Lixian
通讯作者Dong Chuang(dong@dlut.edu.cn)
2006-10-01
发表期刊RARE METALS
ISSN1001-0521
卷号25页码:252-255
摘要A new cluster line approach for the composition rule of Laves phase-related BCC solid solution hydrogen-storage alloys was presented. The cluster line in a ternary phase diagram refers to a straight composition line linking a specific binary cluster to the third element. In the Laves phase-related BCC solid solution alloy system such as Ti-Cr-V, Ti-Cr tends to form binary Cr2Ti Laves phase while Ti-V and Cr-V to form solid solutions. This Laves phase is characterized by a close-packing icosahedral cluster Cr7Ti6. A cluster line Cr7Ti6-V is then constructed in this system. Alloy rods with a diameter of 3 mm of compositions along this line were prepared by copper-mould suction method. The alloy structure is found to vary with the V contents. Furthermore, the P-C-T measurements indicate that the cluster-line (Cr7Ti6)(1-x)V-x alloys have large hydrogen storage capacities.
关键词Ti-Cr-V alloys composition rule cluster hydrogen storage
收录类别SCI
语种英语
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000242948100050
出版者NONFERROUS METALS SOCIETY CHINA
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/87904
专题中国科学院金属研究所
通讯作者Dong Chuang
作者单位1.Dalian Univ Technol, State Key Lab Mat Modificat, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Met Res Inst, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
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Wang Qing,Chen Feng,Wu Jiang,et al. Cluster-based composition rule for Laves phase-related BCC solid solution hydrogen storage alloys[J]. RARE METALS,2006,25:252-255.
APA Wang Qing.,Chen Feng.,Wu Jiang.,Qiang Jianbing.,Dong Chuang.,...&Sun Lixian.(2006).Cluster-based composition rule for Laves phase-related BCC solid solution hydrogen storage alloys.RARE METALS,25,252-255.
MLA Wang Qing,et al."Cluster-based composition rule for Laves phase-related BCC solid solution hydrogen storage alloys".RARE METALS 25(2006):252-255.
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