The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in [Zn(H2O)(6)](BF4)(2): Mn2+ crystal

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	The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in [Zn(H2O)(6)](BF4)(2): Mn2+ crystal
	Liu, Hong-Gang ; Wu, Xiao-Xuan ; Zheng, Wen-Chen ; He, Lv
通讯作者	Zheng, Wen-Chen(zhengwe1@163.com)
	2006-05-01
发表期刊	ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN	0932-0784
卷号	61 期号:5-6 页码:289-292
摘要	The EPR zero-field splitting D (= b(2)(0)) and its pressure and temperature dependence for trigonal Mn2+ centers in low and room temperature phases in [Zn(H2O)(6)](BF4)(2) : Mn2+ crystal are studied by a high-order perturbation formula based on the dominant spin-orbit coupling mechanism. From the studies, the local trigonal distortion angles, the local angular compressibilities and the local angular thermal expansion coefficients for Mn2+ centers in both phases of the [Zn(H2O)(6)](BF4)(2) crystal are estimated. The results are discussed.
关键词	electron paramagnetic resonance crystal- and ligand-field theory defect structure and properties Mn2+ [Zn(H2O)(6)](BF4)(2)
收录类别	SCI
语种	英语
WOS研究方向	Chemistry ; Physics
WOS类目	Chemistry, Physical ; Physics, Multidisciplinary
WOS记录号	WOS:000239423700013
出版者	VERLAG Z NATURFORSCH
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/88078
专题	中国科学院金属研究所
通讯作者	Zheng, Wen-Chen
作者单位	1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Civil Aviat Flying Inst China, Dept Phys, Guanghan 618307, Peoples R China 3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Liu, Hong-Gang,Wu, Xiao-Xuan,Zheng, Wen-Chen,et al. The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in [Zn(H2O)(6)](BF4)(2): Mn2+ crystal[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,2006,61(5-6):289-292.
APA	Liu, Hong-Gang,Wu, Xiao-Xuan,Zheng, Wen-Chen,&He, Lv.(2006).The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in [Zn(H2O)(6)](BF4)(2): Mn2+ crystal.ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,61(5-6),289-292.
MLA	Liu, Hong-Gang,et al."The EPR zero-field splitting D and its pressure and temperature dependence for trigonal Mn2+ centers in [Zn(H2O)(6)](BF4)(2): Mn2+ crystal".ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 61.5-6(2006):289-292.