Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)(6)](2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures

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	Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)(6)](2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures
	Li, Hu-Fang 1; Kuang, Xiao-Yu 1,2; Wang, Huai-Qian 1; Mao, Ai-Jie 1
通讯作者	Li, Hu-Fang(seu_kxy@163.com)
	2008-09-01
发表期刊	ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN	0932-0784
卷号	63 期号:9 页码:609-615
摘要	The local octahedral environment of Ni2+ in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O crystals with a trigonal distortion has been studied at different temperatures, based on the complete energy matrices. The calculated results showed that the local lattice structure around an octahedral Ni2+ centre in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O exhibits at compression distortion. Simultaneously, the orbital reduction effect on the g factors has been studied. The relationship between Ag =g(parallel to) -g(perpendicular to) and orbital reduction fractor k at 4.2.77 and 298 (302) K has been discussed. suggesting, that there is an almost linear relation between k and Delta g in Ni2+ ion in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O at each temperature.
关键词	Local Structure Orbital Reduction Effect EPR Spectrum Complete Energy Matrices
收录类别	SCI
语种	英语
WOS研究方向	Chemistry ; Physics
WOS类目	Chemistry, Physical ; Physics, Multidisciplinary
WOS记录号	WOS:000259901400013
出版者	VERLAG Z NATURFORSCH
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/94212
专题	中国科学院金属研究所
通讯作者	Li, Hu-Fang
作者单位	1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Li, Hu-Fang,Kuang, Xiao-Yu,Wang, Huai-Qian,et al. Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)(6)](2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,2008,63(9):609-615.
APA	Li, Hu-Fang,Kuang, Xiao-Yu,Wang, Huai-Qian,&Mao, Ai-Jie.(2008).Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)(6)](2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures.ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,63(9),609-615.
MLA	Li, Hu-Fang,et al."Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)(6)](2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures".ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 63.9(2008):609-615.