Crystallographic Tailoring of Graphene by Nonmetal SiOx Nanoparticles

doi:10.1021/ja906610e

IMR OpenIR

	Crystallographic Tailoring of Graphene by Nonmetal SiOx Nanoparticles
	Gao, Libo; Ren, Wencai; Liu, Bilu; Wu, Zhong-Shuai; Jiang, Chuanbin; Cheng, Hui-Ming
通讯作者	Ren, Wencai(wcren@imr.ac.cn)
	2009-10-07
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN	0002-7863
卷号	131 期号:39 页码:13934-+
摘要	In this communication, we demonstrate nonmetal SiOx nanoparticles (NPs) can tailor few-layer graphenes (FLGs) into graphene nanoribbons (GNRs) and regular pieces with smooth edges. The tailoring of graphene is realized by the movements of SiOx NPs along the graphene lattice in the atmosphere of H-2, and the tailored trenches exhibit high selectivity of the crystallographic orientation compared to the reported metal. NPs. The low tailoring rate and the tong lifetime provide great potential for accurate control of the trench length or the length of the tailored GNRs. As a result, smooth GNRs with a length of several micrometers and a width narrower than 10 nm are obtained. A catalytic hydrogenation mechanism is proposed for the tailoring of graphene by SiOx NPs. These findings open up the possibility for atomically precise graphene device fabrication without metal, contamination and indicate the potential catalytic activity of nonmetal Nips for the hydrogenation of carbon materials.
资助者	MOST of China ; NSFC ; CAS
DOI	10.1021/ja906610e
收录类别	SCI
语种	英语
资助项目	MOST of China[2006CB932701] ; NSFC[50872136] ; NSFC[50972147] ; NSFC[90606008] ; CAS[KJCX2-YW-M01]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000270433900025
出版者	AMER CHEMICAL SOC
引用统计	被引频次：69[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/97148
专题	中国科学院金属研究所
通讯作者	Ren, Wencai
作者单位	Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Gao, Libo,Ren, Wencai,Liu, Bilu,et al. Crystallographic Tailoring of Graphene by Nonmetal SiOx Nanoparticles[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2009,131(39):13934-+.
APA	Gao, Libo,Ren, Wencai,Liu, Bilu,Wu, Zhong-Shuai,Jiang, Chuanbin,&Cheng, Hui-Ming.(2009).Crystallographic Tailoring of Graphene by Nonmetal SiOx Nanoparticles.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,131(39),13934-+.
MLA	Gao, Libo,et al."Crystallographic Tailoring of Graphene by Nonmetal SiOx Nanoparticles".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 131.39(2009):13934-+.