In situ formation and rapid decomposition of Ti(BH4)(3) by mechanical milling LiBH4 with TiF3

doi:10.1063/1.3076106

IMR OpenIR

	In situ formation and rapid decomposition of Ti(BH4)(3) by mechanical milling LiBH4 with TiF3
	Fang, Z. Z.; Ma, L. P.; Kang, X. D.; Wang, P. J.; Wang, P.; Cheng, H. M.
通讯作者	Wang, P.(pingwang@imr.ac.cn)
	2009-01-26
发表期刊	APPLIED PHYSICS LETTERS
ISSN	0003-6951
卷号	94 期号:4 页码:3
摘要	Mechanically milled 3LiBH(4)/TiF3 mixture can rapidly release over 5 wt % hydrogen at moderate temperatures (70-90 degrees C) without undesired gas impurity. Structure analyses results show that the favorable dehydrogenation performance of the material should be associated with the in situ formation and rapid decomposition of an intermediate titanium borohydride (Ti(BH4)(3)). These findings demonstrated a viable chemical activation approach for promoting hydrogen release from the thermodynamically stable borohydrides. Particularly, it shows the potential of transition metal borohydrides for hydrogen storage applications.
关键词	boron compounds dissociation hydrogen storage hydrogenation lithium compounds milling titanium compounds
资助者	Hundred Talents Project of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; CAS President Prize winner
DOI	10.1063/1.3076106
收录类别	SCI
语种	英语
资助项目	Hundred Talents Project of the Chinese Academy of Sciences ; National Natural Science Foundation of China[50571099] ; National Natural Science Foundation of China[50671107] ; National Natural Science Foundation of China[50771094] ; National Natural Science Foundation of China[50801059] ; CAS President Prize winner
WOS研究方向	Physics
WOS类目	Physics, Applied
WOS记录号	WOS:000262971800125
出版者	AMER INST PHYSICS
引用统计	被引频次：51[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/98712
专题	中国科学院金属研究所
通讯作者	Wang, P.
作者单位	Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Fang, Z. Z.,Ma, L. P.,Kang, X. D.,et al. In situ formation and rapid decomposition of Ti(BH4)(3) by mechanical milling LiBH4 with TiF3[J]. APPLIED PHYSICS LETTERS,2009,94(4):3.
APA	Fang, Z. Z.,Ma, L. P.,Kang, X. D.,Wang, P. J.,Wang, P.,&Cheng, H. M..(2009).In situ formation and rapid decomposition of Ti(BH4)(3) by mechanical milling LiBH4 with TiF3.APPLIED PHYSICS LETTERS,94(4),3.
MLA	Fang, Z. Z.,et al."In situ formation and rapid decomposition of Ti(BH4)(3) by mechanical milling LiBH4 with TiF3".APPLIED PHYSICS LETTERS 94.4(2009):3.